6. (a) Based on molecular orbital theory explain the formation of bonding and anti-bonding molecular orbitals. (b) Consider two elements X and Y .Their electron affinity (Ea) values are given as Element Ea (KJ/mol) 300 Y 75 i) If the elements X and Y form X and Y ions, formation of which ion will liberate more energy .Why? i) Assuming that they are in the same period, which element would have smaller ionization energy and why? Explain
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6. (a) Based on molecular orbital theory explain the formation of bonding and anti-bonding molecular orbitals....
Which of the following statements concerning molecular orbital theory is/are true? 1. Bonding orbitals are equal in energy to their corresponding anti-bonding orbitals. 2. Adding electrons to anti-bonding orbitals destabilizes molecules. 3. Unlike when we fill atomic orbitals, we DON'T use Hund's Rule to fill molecular orbitals. Group of answer choices
Band theory is an extension of molecular orbital theory. According to band theory, atomic orbitals between atoms in a sample form a nearly continuous band of molecular orbitals. In a metal, the bottom half of the band is composed of bonding molecular orbitals and the top half of the band Is composed of anti-bonding molecular orbitals. Transition metals from the 4th period have a band of molecular orbitals formed from a composite of 4s and 3d orbitals. Metallic properties, including...
3. According to molecular orbital theory, how many re-bonding molecular orbitals are there for benzene? 4. According to molecular orbital theory, how many Tt-antibonding molecular orbitals are there for benzene? 5. According to molecular orbital theory, how many non-bonding molecular orbitals are there for benzene?
2. Use the group orbitals of CH3 and CH2 to create a Qualitative Molecular Orbital Theory diagram of the bonding in CH3NH2 (14 electrons) Draw a separate picture attempting to illustrate what the molecular orbital will look like A few points to help you in making this diagram: • Better overlap (as in head-on versus side-by-side) leads to greater stabilization of bonding orbital • If bonding interaction is highly stabilized, the anti-bonding interaction is even more destabilized • The 2p...
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5. According to molecular orbital theory, what type of bonding orbitals exists for diatomie hydrogen? a. A sigma bonding orbital and a sigma antibonding orbital b. Two sigma bonding orbitals C. A sigma bonding and a pi bonding orbital d. A sigma orbital and a pi antibonding orbital
2. According to molecular orbital theory, how many molecular orbitals of benzene are bonding. antibonding and nonbonding? A. Two bonding, two antibonding and two nonbonding B. Three bonding, two antibonding and one nonbonding C. Three bonding, three antibonding and cro nonbonding D. Two bonding, zero antibonding and four nonbonding E Six bonding, zero antibonding and zero nonbonding 3. Which one of the following is aromatic? A. II B. III C. IV D. I E. None
Shade the following orbitals to represent the bonding, non-bonding, and anti-bonding character of the HOMO and LUMO molecular orbitals. b. 83 dyz XZ d22 83 d,2-y2 dxy Invoking molecular orbitals, explain why the electrochemical oxidation of ferrocene is reversible. c.
Shade the following orbitals to represent the bonding, non-bonding, and anti-bonding character of the HOMO and LUMO molecular orbitals. b.
83 dyz XZ d22 83 d,2-y2 dxy Invoking molecular orbitals, explain why the electrochemical oxidation of ferrocene is reversible. c.
Please explain.
0/4 pts Question 5 Electrons exist in orbitals within an atom. Bohr's model described a single electron system well. But the energy level for orbitals change when as you add a second and more electron. In a single electron system, there are (a)_orbital(s) at the n-2 level. These n-2 orbital(s) exist at (b) sub-level(s) in the atom. In a multi-electron system, (c)_orbital(s) at the n-2 level. These n-2 orbital(s) exist at (d)sub-level(s) in the atom. Bohr was never...
The molecular orbital diagrams of hydrogen and helium can tell us a lot about how these elements interact and behave. The MO diagram for H2 is below. Before bonding, each neutral hydrogen atom contains one electron in a 1s orbital. The in-phase overlap of these orbitals generates Select a sigma bonding orbital that is lower in energy than an H 1s orbital a sigma bonding orbital that is higher in energy than an H 1s orbital a pi bonding orbital...
a) Briefly explain the practical importance of the Born-Openheimer approximation in the theory of molecular structure. [4] b) For the B2 molecule in its ground state, determine i. The molecular orbital electron configuration [2] ii. The bond order [1] i. The term symbol [3] c) Use the electron configurations of NO and N, which is likely to have a shorter bond length [6] El (s+v2p) d) Show that the sp2 hybrid orbital normalized and orthogonal. is normalized if s and...