Solution :-
following image shows the classification of the element with the band theory prediction of the energy and band gap
Band theory is an extension of molecular orbital theory. According to band theory, atomic orbitals between...
Which of the following statements concerning molecular orbital theory is/are true? 1. Bonding orbitals are equal in energy to their corresponding anti-bonding orbitals. 2. Adding electrons to anti-bonding orbitals destabilizes molecules. 3. Unlike when we fill atomic orbitals, we DON'T use Hund's Rule to fill molecular orbitals. Group of answer choices
1.According to molecular orbital theory, the destructive interference of two atomic orbitals results in a(n) 2.According to molecular orbital theory, the constructive interference of two atomic orbitals results in a(n)
3. According to molecular orbital theory, how many re-bonding molecular orbitals are there for benzene? 4. According to molecular orbital theory, how many Tt-antibonding molecular orbitals are there for benzene? 5. According to molecular orbital theory, how many non-bonding molecular orbitals are there for benzene?
4. On the basis of molecular orbitals and molecular orbital diagrams, predict which molecule in each series will have the longest bond. Be sure to provide a brief explanation a. B2, B2 b. 02*, 0,- c. HHe", Hz 5. Consider the hydroxide ion, OH and do the following: a. Prepare a molecular orbital diagram and fill with electrons given the following atomic orbital potential energies: O(2s) = -32.3 eV, O(2p) = -15.8 eV, H(s) -13.6 eV. Be sure to label...
5 5. According to molecular orbital theory, what type of bonding orbitals exists for diatomie hydrogen? a. A sigma bonding orbital and a sigma antibonding orbital b. Two sigma bonding orbitals C. A sigma bonding and a pi bonding orbital d. A sigma orbital and a pi antibonding orbital
2. Use the group orbitals of CH3 and CH2 to create a Qualitative Molecular Orbital Theory diagram of the bonding in CH3NH2 (14 electrons) Draw a separate picture attempting to illustrate what the molecular orbital will look like A few points to help you in making this diagram: • Better overlap (as in head-on versus side-by-side) leads to greater stabilization of bonding orbital • If bonding interaction is highly stabilized, the anti-bonding interaction is even more destabilized • The 2p...
6. (a) Based on molecular orbital theory explain the formation of bonding and anti-bonding molecular orbitals. (b) Consider two elements X and Y .Their electron affinity (Ea) values are given as Element Ea (KJ/mol) 300 Y 75 i) If the elements X and Y form X and Y ions, formation of which ion will liberate more energy .Why? i) Assuming that they are in the same period, which element would have smaller ionization energy and why? Explain
2. According to molecular orbital theory, how many molecular orbitals of benzene are bonding. antibonding and nonbonding? A. Two bonding, two antibonding and two nonbonding B. Three bonding, two antibonding and one nonbonding C. Three bonding, three antibonding and cro nonbonding D. Two bonding, zero antibonding and four nonbonding E Six bonding, zero antibonding and zero nonbonding 3. Which one of the following is aromatic? A. II B. III C. IV D. I E. None