2. Use the group orbitals of CH3 and CH2 to create a Qualitative Molecular Orbital Theory...
2. Use the group orbitals of CH3 and CH2 to create a Qualitative
Molecular Orbital Theory diagram of the bonding in CH3NH2 (14
electrons)
Draw a separate picture attempting to illustrate what the molecular
orbital will look like A few points to help you in making this
diagram:
• Better overlap (as in head-on versus side-by-side) leads to
greater stabilization of bonding orbital
• If bonding interaction is highly stabilized, the anti-bonding
interaction is even more destabilized
• The 2p orbitals of oxygen are lower than the p orbital of the CH3
group and of similar energy to the sigma(out) orbital
• Your molecular orbital picture should have multiple lobes created
by favorable overlap and nodes created where there is unfavorable
overlap
Homework Answers
This is a qualitative Molecular orbital of CH3NH2 where energy is not to scale.
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2. Use the group orbitals of CH3 and CH2 to create a Qualitative
Molecular Orbital Theory...
Sketch the qualitative molecular orbital energy diagram for water. Inclu symmetry labels for each...
Sketch the qualitative molecular orbital energy diagram for water. Inclu symmetry labels for each molecular orbital. Indicate whether each molecular bonding, nonbonding, or anti-bonding and don't forget the σ and π labels. Remember to construct appropriate group orbitals from the outer H-atoms. Describe the bonding of this molecule from the MO diagram you constructed, including the location s) of the lone pair(s). The 2s and 2p energies for oxygen are -26 and -13 eV, respectively, and the ls energy of...
Consider two 2p orbitals, one on each of two different atoms, that are oriented side-to-side as...
Consider two 2p orbitals, one on each of two different atoms, that are oriented side-to-side as in the figure. Imagine bringing these nuclei together so that overlap occurs as shown in the figure. This overlap results in a system of molecular orbitals, 88-8. Construct an orbital interaction diagram for molecular orbital formation using the images that represent various orbital types (e.g., atomic, bonding, antibonding). Additionally, identify the number of nodes in each atomic and molecular orbital. Answer Bank
4. On the basis of molecular orbitals and molecular orbital diagrams, predict which molecule in each...
4. On the basis of molecular orbitals and molecular orbital diagrams, predict which molecule in each series will have the longest bond. Be sure to provide a brief explanation a. B2, B2 b. 02*, 0,- c. HHe", Hz 5. Consider the hydroxide ion, OH and do the following: a. Prepare a molecular orbital diagram and fill with electrons given the following atomic orbital potential energies: O(2s) = -32.3 eV, O(2p) = -15.8 eV, H(s) -13.6 eV. Be sure to label...
Consider two 2p orbitals, one on each of two different atoms, oriented side-to-side, as in the...
Consider two 2p orbitals, one on each of two different atoms, oriented side-to-side, as in the figure. Imagine bringing these nuclei together so that overlap occurs as shown in the figure. This overlap results in a system of molecular orbitals. (Scroll down to answer part "c)".) a) Below, construct an orbital interaction diagram for molecular orbital formation by dragging the images triat represent various orbital types (e.g., atomic, bonding, antibonding) into the relevant boxes. b) Identify the number of nodes in each...
Band theory is an extension of molecular orbital theory. According to band theory, atomic orbitals between...
Band theory is an extension of molecular orbital theory. According to band theory, atomic orbitals between atoms in a sample form a nearly continuous band of molecular orbitals. In a metal, the bottom half of the band is composed of bonding molecular orbitals and the top half of the band Is composed of anti-bonding molecular orbitals. Transition metals from the 4th period have a band of molecular orbitals formed from a composite of 4s and 3d orbitals. Metallic properties, including...
The molecular orbital diagrams of hydrogen and helium can tell us a lot about how these...
The molecular orbital diagrams of hydrogen and helium can tell us a lot about how these elements interact and behave. The MO diagram for H2 is below. Before bonding, each neutral hydrogen atom contains one electron in a 1s orbital. The in-phase overlap of these orbitals generates Select a sigma bonding orbital that is lower in energy than an H 1s orbital a sigma bonding orbital that is higher in energy than an H 1s orbital a pi bonding orbital...
Which of the following statements concerning molecular orbital theory is/are true? 1. Bonding orbitals are equal in ener...
Which of the following statements concerning molecular orbital theory is/are true? 1. Bonding orbitals are equal in energy to their corresponding anti-bonding orbitals. 2. Adding electrons to anti-bonding orbitals destabilizes molecules. 3. Unlike when we fill atomic orbitals, we DON'T use Hund's Rule to fill molecular orbitals. Group of answer choices
13. (14 pts) MO Theory Draw the complete (core and valence) molecular orbital energy level diagram...
13. (14 pts) MO Theory Draw the complete (core and valence) molecular orbital energy level diagram for the homonuclear diatomic molecule Be2. Use standard MO symbols to label the energy levels (That is: o, o, , or n*, as needed, with subscripts indicating which atomic orbitals formed them.) a. Sketch the molecular orbital formed when two 2p orbitals, one each on each Be atom, overlap to form a o antibonding MO b. Using your MO energy level diagram in (a),...
Draw molecular orbital energy level diagram for CH3 by following the steps given below. Valance orbital...
Draw molecular orbital energy level diagram for CH3 by following the steps given below. Valance orbital ionization potentials: H(1s) - 13.6 eV, C(2s) -19.5 eV, C(2p) -10.7 ev. (6C, 11) E x +y?,z? 1 1 1 203 3C on 1 1 1 1 1 1 1 T - 1 0 2 1 1 -1 | 1 -1 1 -1 -1 TOT- 2 25; 1 1 - 1 1 -1 1 -1 1 30, 1 1 1 -1 0 1 -1...
question 1 2 3 4 5 6 Which are correct? In molecular orbital (MO) energy level...
question 1 2 3 4 5 6
Which are correct? In molecular orbital (MO) energy level diagram for cyanide ion? The MO shows: (a) bond order = 2 (b) bonder order =3 ) cyanide ion is paramagnetic ) cyanide ion is! diamagnetic (e) HOMO is nu HOMO is og (6%) (2) Write down the diatomic molecules 2p orbitals for (a), (b), (6%) (3) What is the bond order of (a) OF(b) to which atom ( O or F ) the...
Sketch the qualitative molecular orbital energy diagram for water. Inclu symmetry labels for each molecular orbital. Indicate whether each molecular bonding, nonbonding, or anti-bonding and don't forget the σ and π labels. Remember to construct appropriate group orbitals from the outer H-atoms. Describe the bonding of this molecule from the MO diagram you constructed, including the location s) of the lone pair(s). The 2s and 2p energies for oxygen are -26 and -13 eV, respectively, and the ls energy of...
Consider two 2p orbitals, one on each of two different atoms, that are oriented side-to-side as in the figure. Imagine bringing these nuclei together so that overlap occurs as shown in the figure. This overlap results in a system of molecular orbitals, 88-8. Construct an orbital interaction diagram for molecular orbital formation using the images that represent various orbital types (e.g., atomic, bonding, antibonding). Additionally, identify the number of nodes in each atomic and molecular orbital. Answer Bank
4. On the basis of molecular orbitals and molecular orbital diagrams, predict which molecule in each series will have the longest bond. Be sure to provide a brief explanation a. B2, B2 b. 02*, 0,- c. HHe", Hz 5. Consider the hydroxide ion, OH and do the following: a. Prepare a molecular orbital diagram and fill with electrons given the following atomic orbital potential energies: O(2s) = -32.3 eV, O(2p) = -15.8 eV, H(s) -13.6 eV. Be sure to label...
Band theory is an extension of molecular orbital theory. According to band theory, atomic orbitals between atoms in a sample form a nearly continuous band of molecular orbitals. In a metal, the bottom half of the band is composed of bonding molecular orbitals and the top half of the band Is composed of anti-bonding molecular orbitals. Transition metals from the 4th period have a band of molecular orbitals formed from a composite of 4s and 3d orbitals. Metallic properties, including...
The molecular orbital diagrams of hydrogen and helium can tell us a lot about how these elements interact and behave. The MO diagram for H2 is below. Before bonding, each neutral hydrogen atom contains one electron in a 1s orbital. The in-phase overlap of these orbitals generates Select a sigma bonding orbital that is lower in energy than an H 1s orbital a sigma bonding orbital that is higher in energy than an H 1s orbital a pi bonding orbital...
13. (14 pts) MO Theory Draw the complete (core and valence) molecular orbital energy level diagram for the homonuclear diatomic molecule Be2. Use standard MO symbols to label the energy levels (That is: o, o, , or n*, as needed, with subscripts indicating which atomic orbitals formed them.) a. Sketch the molecular orbital formed when two 2p orbitals, one each on each Be atom, overlap to form a o antibonding MO b. Using your MO energy level diagram in (a),...
Draw molecular orbital energy level diagram for CH3 by following the steps given below. Valance orbital ionization potentials: H(1s) - 13.6 eV, C(2s) -19.5 eV, C(2p) -10.7 ev. (6C, 11) E x +y?,z? 1 1 1 203 3C on 1 1 1 1 1 1 1 T - 1 0 2 1 1 -1 | 1 -1 1 -1 -1 TOT- 2 25; 1 1 - 1 1 -1 1 -1 1 30, 1 1 1 -1 0 1 -1...
question 1 2 3 4 5 6
Which are correct? In molecular orbital (MO) energy level diagram for cyanide ion? The MO shows: (a) bond order = 2 (b) bonder order =3 ) cyanide ion is paramagnetic ) cyanide ion is! diamagnetic (e) HOMO is nu HOMO is og (6%) (2) Write down the diatomic molecules 2p orbitals for (a), (b), (6%) (3) What is the bond order of (a) OF(b) to which atom ( O or F ) the...
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