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Mineral: Almandine Formula: Fe3Al2(SiO4)3 -Show where each of the cations in the formula are housed &...

Mineral: Almandine

Formula: Fe3Al2(SiO4)3

-Show where each of the cations in the formula are housed & describe where the M1 and M2 cations are located in this crystal system.

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Answer #1

Almandine consists of groups of independent, distorted SiO4 tetrahedrons, each of which is linked, by sharing corners, to distorted M2O6 (M2=aluminum) octahedrons, thus forming a three-dimensional framework. The interstices are occupied by M1 divalent metal ions ( M1= Fe2+), so that each one is surrounded by eight oxygen atoms that are at the corners of a distorted cube. Therefore, each oxygen is coordinated by two M1, one M2, and one silicon cation. The configuration of the array is such that Almandines are isometric (cubic).

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