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Is PPh3 a stronger pi acceptor than NO or CO? Confused because my IR displays a...

Is PPh3 a stronger pi acceptor than NO or CO? Confused because my IR displays a stronger upfield shift in the IR when theres a PPh3. The compound (MeC5H4)Mn(CO)3 has a carbonyl stretch at 1932 whereas the carbonyl stretch for [(MeC5H4)Mn(CO)(NO)(PPh3)][PF6] is 2023. Someone explain please.

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Co Mete A) 1.9-32-led) ra) 2023 [CM ; o the cnd

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