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Which species will reduce Mn3+ to Mn2+ (Ecell = 1.51 V) but will NOT reduce Cr3+...

Which species will reduce Mn3+ to Mn2+ (Ecell = 1.51 V) but will NOT reduce Cr3+ to Cr2+ (Ecell = -0.40 V)? (Can you explain with steps on how to find the correct answer, and why the other answers are not correct?)

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Answer #1

Mn3+   + e- -----------------> Mn2+ Eo = 1.51 V . to get this reaction other reaction must be oxidiation . for that the reduction potential should be less than 1.51 V. so all have less than 1.51 V so that all given elements can reduce Mn3+

now Cr3+ + e- ------------------> Cr2+. , Eo = -0.40 V

which should not occur means reduction potential more than -0.40 V.    Zn and Pb can reduce Cr3+ because they have lower reduction potentials   but not Pb

so answer A) Pb only

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