Write the products of the reactions showing the mechanism. 4. (benzene) heat +SoCl2 NH2 5. CN...
Write curved arrow mechanisms for TWO of the following reactions. CN CH NH2 1. LiAlH4 a) 2. H2O 3. OH CN COOH H2SO4/H20 b) heat
4. Draw the mechanism for the reaction of benzene with Et and base. 5. Draw the mechanism for the reaction of propanal with CN/HCN. ... unalauda in the correct acometry showing its orbitals
Provide the major products for the following reactions.
COOMe heat COOMe CN heat 2) H3C heat 3) 1 eq 4) OMe heat
draw final products, mechanisms
and intermediates
c) 1. CH3CH2CI, AICI: 2. KMnO4 3. SOCl2, pyridine 4. H2N-CH2CH3 , pyridine 5. LiAlH4 6. H307 workup
Showing mechanism and major product is extremely appreciated.
Thank you in advance!
B) Predict the products for the reactions below (2 points per box, 4 points total section). MgBr SH Major product Major product C) Solve the following boxes below (2 points per box, 6 points total section). 1 equiv HNMez HH 0 LDA
10) Write out the following reactions giving the major organic products, showing the proper regiochemistry and stereochemistry where needed. Give a complete electron (arrow) pushing mechanism under the reactions where asked to do so. Label all appropriate mechanisms as SN1, SN2, El or E2 a. trans-2-methylcyclopentanol with HCI. (Give a mechanism) b. trans-1-bromo-2-methylcyclopentane with a methanolic solution of AgNOs. c. iodoethane with sodium cyanide (Na CN). d. 1,2-dimethylcyclobutanol with concentrated sulfuric acid at 95 C (Give a mechanism) e. S-2-bromopentane...
4) Show the products of the below reactions (no mechanism is needed): (10x8=80 points) heat Cro, H,SO, heat SOCI H,SO, cons ARCH + CHCI -
3 Predict the products for the following reactions ( 3 pts each): NO Ci a. AlCh но..//> HNOg MgBr ether C. H3O+ Br 1 H2N NH2 DMF d) 2. NaOH, H20 4. If you were to nitrate chlorobenzene what would be the product or products that would be formed. Is nitration of chlorobenzene regioselective why or why not. Please explain your answer showing resonance structures. (5 pts)
4. Write the products of the following reactions. If there is no reaction write NR. (22 points, 2 each). CH.CH.CH, OH + CHỊCH,CH-NH - ne: - n + (1) 2 CH CH CHL water + (1) CH.CH.CH wa CH, CH H alysis (1) LAIH (2) HCl in water (DLAH in water (B2CH.CH Meter 7 -CN (1) CH, CHIM, (2) HCl in water
14. (4 points each) Complete the following reactions showing the major organic product). 2 CH,NH CH CH,OH Ci pyridine 2. 2CH,NH2 Ci AICl I. excess CH,MgBr 2. H CH,CH,CH OH NaOH
14. (4 points each) Complete the following reactions showing the major organic product). 2 CH,NH CH CH,OH Ci pyridine 2. 2CH,NH2 Ci AICl I. excess CH,MgBr 2. H CH,CH,CH OH NaOH