22.Ans:- Option (A) " 0.40 " is the correct answer.
Explanation :-
Given base dissociation constant (Kb) of CH3NH2 = 4.4 x 10-4
pKb CH3NH2 = - log Kb
= - log 4.4 x 10-4
= 3.36
Given, pH = 10.24
Using Henderson-Hasselbalch equation :
pOH = pKb + log [Salt] / [Base]
Because ,
pH + pOH = 14
pOH = 14 - pH
So,
14 - pH = 3.36 + log [CH3NH3Cl] / [CH3NH2]
14 - 10.24 = 3.36 + log [CH3NH3Cl] / [CH3NH2]
3.76 = 3.36 + log [CH3NH3Cl] / [CH3NH2]
log [CH3NH3Cl] / [CH3NH2] = 3.76 - 3.36
log [CH3NH3Cl] / [CH3NH2] = 0.40
[CH3NH3Cl] / [CH3NH2] = 100.40
[CH3NH3Cl] / [CH3NH2] = 2.51
Reciprocal on both the sides
[CH3NH2] / [CH3NH3Cl] = 1/2.51
[CH3NH2] / [CH3NH3Cl] = 0.40
Hence, ratio of CH3NH2 to CH3NH3Cl = 0.40 |
So, option (A) is the correct answer.
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