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Y B H20 () 1. Mg, anhydrous other 2. MOD сна, кон (CH) Cuti (1) Hg(OA)....
YS 32311 CH, CHO + CH,COCH,CHE F G 1) og 1 2) (CH), 1) Hg(OAc)2, H20 2) NaBH, 11. Complete this reaction map by providing structures of missing compounds, intermediates or reaction conditions A-l. Please note they are all unique and not repeated (10 points). 1) Hg(OAc)2, H20 2) NaBH, А 1) BH3 2) H202, NaOH 1) BH3 2) H202, NaOH enit 3, 50 points max Intermediate(s) m
What is the expected major product for the following reaction? 1. Hg(OA), H20 2. NaBH, NaOH 79 + enantiomer OH TOH + enantiomer
Suggest a mechanism for the following electrophilic addition
reaction
OH 1) Hg(OAC)2, anhydrous THE 2) NaBH, then hydrolysis
2. Predict the product. CH,CH2NH2 1. LIAIH NH 2. H20 Н,о" Br КОН NH 1. excess CH3I 2. Ag20, H20 heat
complete the starburst
1. Complete the following starbursts. |BrH.о сьCH,с снC, кон )OsO 2) Zn, H 1) Hg(Олс, Н,ОТНE 2) NaBH НВе CH ZniCu) Н, Рю, ether КМпо, н" НС с, н.о 1) вн, ТHF 2) Н-О, Он- СHC, КОН 1) Oо, NMO 2) Ню, НСТ |сн.СOOОН
1. Complete the following starbursts. |BrH.о сьCH,с снC, кон )OsO 2) Zn, H 1) Hg(Олс, Н,ОТНE 2) NaBH НВе CH ZniCu) Н, Рю, ether КМпо, н" НС с, н.о 1) вн, ТHF 2)...
1. CH MgBr 2. HO 1. (CH3),Cuti 2. H2O 1. CHg MgBr 2. H20 1. (CH3)2NH 2. H20 2. H20 1. CH CHANH, OCH,CHE 2 HO CH OH • Sul
2. What is the major product for the following reaction? a. Hg(OAc)2, H20 b. NaBH, NaOH + enantiomer A) B) C) OH E) More than one of these choices.
6 Identify the major HO product of this reaction. CH, H2SO4 (A) -CH; (B) -CH (C) CH (D) -CH R 7 Identify a reagent or set of reagents to accomplish the following transformation OH (A) Oso i-BOOH (B) 1) Hg(OAc), H2O 2) NaBH (D) HOOH (C) 1) THF.BH; 2) H2O2 OH H20 Δ
1) Provide the starting material for the following reaction. (0.5 pts) Он Он 1) Hg(OAc)2, H20 2) NaBH (provide starting material) 2) Provide the major organic product(s) for the following reactions. If stereoisomers are formed, please show both stereoisomers. (0.5 pts each) 1) BH3 THF a) 2)120 NaOH 1) NaOH, H-O, 55°C b) 2) OsO4 t-BuOOH 1-BuOH, NaOH Br2 c) CCl4 H2O, H2SO d) H9SO4 2 equivalents HBr e) 3) The following ction generates an ether. Provide the major organic...
1) R'-MgBr in THF 2)H,o NaH Ho or OH PAA X2. H20 1) Hg(OAc)2, R'OH 2) NaBH4, NaOH, H20 Os0 NaHSO, H2O I) 2)CH, SCH HyIO HBr ROOR 1)BH3. THF 2)H202, NaOH, H2O Mg, THF PBr3 NaOH )OTHF 2) H30 CrOj. H,SO, 1) NaH 2)RXDMF "О-R DMF PCC DCM ) THF 2) H3O+ SOCI pyridine Li Hexanes