3. t Suggest a synthesis for the following alcohols starting from an aldchyde or a etone...
Suggest a synthesis for each alcohol, starting from an aldehyde
or a ketone and an appropriate Grignard reagent (the number of
combinations of Grignard reagent and aldehyde or ketone that might
be used is shown in parentheses below each target molecule):
(Two combinations) 1. CH3MgBr in ether 2. Hz0+ 1. B in ether H 2.H30* Structure A: ? Edit Structure B: (Two combinations) MgBr 1. ether + C 2. H30 1. E in ether 2. H30* 1. CHM9Br in ether...
Show how you would use Grignard syntheses to prepare the
following alcohols from the indicated starting materials and any
other necessary reagents. Draw the Grignard reagent and any other
organic reagents needed.
11 RUVIUWI Constans i Pendulu Part F Show how you would use Grignard syntheses to prepare the following alcohols from the indicated starting materials and any other necessary reagents. Draw the Grignard reagent and any other organic reagents needed. ОН -C-CH CH, from C-OCH.CH Draw the molecules on...
The following synthesis is done in 3 steps.
1. The selective oxidation of alcohols.
2. Aromatic Grignard
3. Carbon-Carbon coupling.
Perform stoichiometric calculations to obtain 1 ml of
the final product, using the concept of limit reagent in the
synthesis of geranial and phenylmagnesium bromide. assuming 100%
yield.
The complete equations of the synthesis of geranial and
grignard reagent are shown below. (They are needed to calculate the
final 1 ml of product of the reaction above)
Density of Final...
Design a synthesis of ethyl 2-ethyl-3-oxohexanoate from alcohols containing 4 carbons or fewer. points COET alcohols containing 4 carbons or fewer Part 1 out of 9 Choose the best option for the precursor to the target molecule. Part 2 out of 9 19 Choose the best option for the carboxylic acid precursor to the intermediate ethyl butanoate. points TOET OET carboxylic acid alcohol oị © © carboxylic acid alcohol points ОН он о носH,CH, но Design a synthesis of ethyl...
Tertiary alcohols with two identical alkyl groups attached to
the alcohol carbon can be made either from an ester and two moles
of a Grignard reagent, or from a ketone and one mole of a Grignard
reagent. Use retrosynthetic analysis to suggest one path of each
type to synthesize 2-methyl-2-butanol. (Click and drag the
appropriate image to the correct position in the following
reactions.)
Tertiary alcohols with two identical alkyl groups attached to the alcohol carbon can be made either...
Use retrosynthetic analysis to suggest two paths to synthesize 2-methyl-3-pentanol using the Grignard reaction. (Click and drag the appropriate image to the correct position in the following reactions.) Aldehyde Grignard route 1 MgBr OH H,O or Aldehyde Grignard 2-methyl-3-pentanol route 2 CH3CH2CH MgBr 0 CH,CHMgBr CHy CH CH,Mg8
Tertiary alcohols with two identical alkyl groups attached to the alcohol carbon can be made either from an ester and two moles of a Grignard reagent, or from a ketone and one mole of a Grignard reagent. Use retrosynthetic analysis to suggest one path of each type to synthesize 1,1-diphenyl-1-propanol. (Click and drag the appropriate image to the correct position in the following reactions.)
For each of the following alcohols, which method of synthesis,
(a) hydroboration?oxidation or (b) oxymercuration?reduction, can
produce the alcohol relatively free of constitutional isomers and
diastereomers? (Drag an alcohol to the appropriate bin if it can be
made by that method.)
r each of the following alcohols, which method of synthesis, (a) hydroboration- oxidation or (b) oxymercuration-reduction, can produce the alcohol relatively free of constitutional isomers and diastereomers? (Drag an alcohol to the appropriate bin ifit can be made by...
Design a synthesis of each of the following from the
starting material as shown
Design a synthesis of each of the following alcohols from the starting material shown. 2. several steps OH several steps OH
The following synthesis is done in 3 steps.
1. The selective oxidation of alcohols.
2. Aromatic Grignard
3. Carbon-Carbon coupling.
Perform stoichiometric calculations to obtain 1 ml of
the final product, using the concept of limit reagent in the
synthesis of geranial and phenylmagnesium bromide. assuming 100%
yield.
The complete equations of the synthesis of geranial and
grignard reagent are shown below. (They are needed to calculate the
final 1 ml of product of the reaction above)
Density of Final...