Shown below is an alternative mechanism for the photochemical chain radical chlorination of methane: Cl_2 +...
Which of the following is a chain propagation step in the free
radical chlorination of methane?
Which of the following is a chain propagation step in the free radical chlorination of methane? A) CH4 +CI-CH3 + HCI B) CI+ CH3 -CH3CI C).CH3 + CH4-CH4+ CH3 D) C12-21
Standard heats reaction values are given for the first three
primary mechanistic steps in the free-radical chlorination of
methane. Explain why the -105kJ/mol overall standard heats of
reaction value for the reaction does not include the standard heats
of reaction value for the initiation step, but instead is the sum
of the standard heats of reaction values for the two propagation
steps.
A. Standard heats of reaction (delta H degree) values are given for the first three primary mechanistic steps...
help with page
23. How is the following step in the free radical chlorination mechanism described *CH3 + 'Cl → CHCI a. initiation step b . termination step c. propagation step d. electrophilic step 24. Which compound would give the following alkene as the major product in an elimination reaction with CH3CH2ONat? ? CHỊCHONa. Br Br 1 3 a. 1 b. 2 c. 3 d. 1 and 3 25. What is the product of the following reaction? OH H2SO4 он...
a) Show the mechanism for the free radical chlorination of
bromopropane. Clearly show the initiation, propagation, and
termination steps.
b) Use the BDEs shown on page 1 to calculate the enthalpy change
for this reaction.
c) Unfortunately, the student’s attempt in question 3 failed,
and he only made traces of 2- chloropropane by using this approach.
What was the major product of the reaction, and explain why it was
formed instead. You may find the BDEs on page 1 to...
pleas help 5,6,7,8,9,10
III IV 5. The product of free-radical halogenation reactions is an alkyl halide. The major amount of this halide forms during the second step of propagation. However, you should be aware that one possible termination step also forms alkyl halides. Why does the majority of the alkyl halide product come from the propagation step and not the termination step? A. At any given time during the reaction, the concentration of both the alkyl radical and the halide...
Mechanisms Question 1 (22 marks) (a) Consider the radical chain reactions of the alkane shown below with Br, in the presence of light. H3C HH H C-CCHS CH3 Br2 hv 2 Different mono- bromo products 25 °C + (you will need to look up the bond dissociation energy (BDE) for the types of bonds formed and broken in this reactions) (i) Give the structures of the products from the reaction and using standard arrow conventions show the series of mechanistic...