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. Fill in the missing reactant(s) and/or product(s) [32 points total 2 points each) 1. CH2MgBr...
Question 3 (20 points) – Fill in the missing reagent, reactant, or product V 1) CH,CVAICI, 2) KMnO4/H2SO4 3 SOCI, CI(3 eq) FeCl2 1) (CH2CH2),Culi 2) H,O/H3O+ Michael Acceptor PCC i. 1) KOC(CH):/HOC(CH): 2) mCPBA الد 3) CH,MgBr 4) H2O/HO* NH A 1) NH, TH,SO4 (cat.) 2) NADH 1) 2) 3)
2. Predict the product. CH,CH NH2 NH 1. LiAlH 2. H20 Br H30 KOH 1. excess CH1 2. Ag20, H20 heat
A-C and bottom question
In the following starting material(s), reagent(s) or product(s) are missing. Fill in the missing material. 1) [H30*), Brz 2) pyridine 1) Bra. PBrg 2) H20 1) Excess NaOH, Excess Bra 2) H30* NaOH Heat о Eto O Heat NaOET OEI 2) H30* DET f.and g. (In your answer include the temperature at which you would you run these reactions?)
Question 3 (20 points) – Fill in the missing reagent, reactant, or product Y 1)CH,CIAICI: 2) KMnO /H, SO 3 SOCI Cl2 (3 eq) Fecig 1) (CH2CH2),Culi 2) H2O/H,O* Michael Acceptor PCC ii.
2) Draw the missing product(s) for each reaction: 2) H3O+ 1) NaBHA 2) H30* 1) LİAİH 2) H30+ 2) H30 1) CH2MgBr (excess) Page 1/3
7. Predict the product of each of the following reactions: (4 points each = 12 points total) 1. NaOEt/EtOH 2. o O Br 0ヘ 3. H3o 4. heat B. 1. NaOEt/EtOH 2. H3O workup C. NH2 1. CHal (excess) 2. Ag20, H20, heat
7. Predict the product of each of the following reactions: (4 points each = 12 points total) 1. NaOEt/EtOH 2. o O Br 0ヘ 3. H3o 4. heat B. 1. NaOEt/EtOH 2. H3O workup C. NH2 1....
Fill in the boxes with the missing major product(s).
1. (20 pts.) Fill in the boxes with the missing major product(s). a. O SOCI2 OH b. H2SO4 heat OH Na2Cr2O7/H+ d. HCI e. (hint: rearrangement!) H2SO4 он heat
1. Predict the product(s) for each of the following reactions: H2SO4 NH2 a. 0 1. H2N-NH2, H2S04, -H20 H 2. KOH/H2O b. MeOH, TsOH он H2O C. H2SO4, -H20 HO d. H2O, H30+ e. H20,H30+ 2. Predict the product and draw the full pushing arrow mechanism for the following reaction NH2 H20,H30+ a. b. 3. Devise an efficient synthesis for the following transformation. HO Br Br
Give the product(s) of reaction of hexanal with each of the following reagents. 2. (0) носн,сн,он, н (b) 1. LIAIH, 2. H,0* (e) NH,он, н" (d) NH,NH2, KOH, heat (e) (CH),СHCH,CH— P(C, Нә» , н" (g) Ag, NH, H,O (h) CrOs, H,SO H,0 () 1. KCN, 2. H,SO MCPBA
Give the product(s) of reaction of hexanal with each of the following reagents. 2. (0) носн,сн,он, н (b) 1. LIAIH, 2. H,0* (e) NH,он, н" (d) NH,NH2, KOH, heat (e) (CH),СHCH,CH—...
3. For each of these molecules, indicate the missing
tautomer.
4. Indicate the product (s) generated and demonstrate their
generation by a mechanism. Included arrows demonstrating the
movement of electrons, partial and formal charges and free
electrons.
ha B) NH D) HONOH o 2 CH3CH2OH, H HOCH2CH2OH, H+ 1) H2NNH2, H2O, NaOH, Heat 2) H20 (11 points) 7.8- PPh3 1) BH3, THF 2) H2O2, NaOH H2O