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Image for An electrochemical cell has a positive standard cell potential but a negative cell potential. Which statement
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Answer #1

E0 = {(R*T)/(n*T)}*lnKc ...........(1)

Also, E = E0 - {(R*T)/(n*T)}*lnQ...........(2)

Thus, from (1) , if E0 > 0

lnKc > 0

or, Kc > 1...........(3)

Also, if E < 0

Then E0 - {(R*T)/(n*T)}*lnQ < 0

or, {(R*T)/(n*T)}*lnQ > E0 > 0

or, lnQ > 0

or, Q > 1 & Q > Kc

Hence the correct option is a) K > 1 ; Q > K

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