![2. The optical activity, measured by specific rotation, of pure (R-malic acid is [a]20D-+27% What is the specific rotation of a mixture of 50% and 50% of (R)-malic acid and (S)-malic acid? What is enantiomeric excess of a sample of malic acid containing both enantiomers that has a [al20D -0% [a]20D-27; [a]20D-_ 13.5: [a]20D-+ 13.5°](http://img.homeworklib.com/questions/2d1ba320-5596-11eb-8051-a593316b00a3.png?x-oss-process=image/resize,w_560)
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2. The optical activity, measured by specific rotation, of pure (R-malic acid is [a]20D-+27% What is...
9. Specific rotation of enantiopure (R)-malic acid is -6. An unknown sample was found to have a s...
9. Specific rotation of enantiopure (R)-malic acid is -6. An unknown sample was found to have a specific rotation of -2 Which isomer is the major component in the unknown mixture? HO OH Malic Acid O OH Circle one: R S What is the enantiomeric excess of the mixture? Show your calculations.
9. Specific rotation of enantiopure (R)-malic acid is -6. An unknown sample was found to have a specific rotation of -2 Which isomer is the major component in...
3. Pure Θ Kaylanoic acid has a specific rotation of-160° (same conditions and temperature as sample...
3. Pure Θ Kaylanoic acid has a specific rotation of-160° (same conditions and temperature as sample above). What is the % optical purity of the sample above ? (0.75 points) 4. 3.5 mg of optically-enriched(-) antibiotic Zachromycin was dissolved in 1.00 mL methanol in a 1.00 mL volumetric flask. The optical rotation was found to be -0.02220 in a 5.0 cm cell. What is the specific rotation? (0.75 points) 5. Calculate the enantiomeric excess and the specific rotation of a...
A student measured the specific rotation of a mixture and found it to be 10.00 degrees....
A student measured the specific rotation of a mixture and found it to be 10.00 degrees. If the specific rotation for the pure R enantiomer is 40.00 degrees, then what is the enantiomeric excess of the solution? What is the actual composition of R and S enantiomers?
3. For the structure below determine the number of stereocenters. Determine the number of stereoisomers for...
3. For the structure below determine the number of stereocenters. Determine the number of stereoisomers for the structure and draw all of them? Determine the enantiomers and which are diasteriomers. Determine the absolute configuration for both for both enantiomers. 10 pts 4. What would be the observed optical rotation of a sample of 3.2 R of pure (.) - 3-chloropentanoic acid with a specific rotation of 30.0 degrees in 100 ml of water, measured in 25 cm cuvette. 4 pts...
The specific rotation of pure (-)-2-butanol is -13.5°. If a mixture has a specific rotation of...
The specific rotation of pure (-)-2-butanol is -13.5°. If a mixture has a specific rotation of +7o, how much of each form (+ and-) is present and what is the e.e. of the mixture? 21. 22. (-)-Lactic acid has a specific rotation of -3.8°. What is the specific rotation of a solution containing 7.5 g of (--lactic acid and 2.5 g of (+)-lactic acid? 23. Draw the Fischer projection of (2R,4R)-2,4-dibromopentane. w? And draw the 24. How many diastereomers are...
optical activity problems.. please show all steps i dont understand You have a sample (Sample X)...
optical activity problems.. please show all steps i dont
understand
You have a sample (Sample X) which is a mixture of +/- Carvone. The solution was made by dissolving 4.50 g of the sample in enough methanol to bring the volume of solution to 10,0 ml. Some of the solution is placed in a 100 cm polarimeter cell and its optical rotation is measured at 25°C using light of the sodium D line wavelength (589.6 nm). The observed rotation is...
7) A solution of an enantiomerically pure sample of (R)- 3-chloropentanoic acid is made by dissolving...
7) A solution of an enantiomerically pure sample of (R)- 3-chloropentanoic acid is made by dissolving 2.5 g of the compound in 100 mL of water. a. Calculate the specific rotation of (R)- 3-chloropentanoic acid if the observed rotation of the above sample is +2.78° when measured in a 40 cm tube. g/mL +2.7% = 127.5 10025(4) b. What is the specific rotation of (S)-3-chloropentanoic acid? -27,8 c. A chemist prepares a sample which is a mixture of both enantiomers...
11. Enantiopurity - How pure a substance is in one enantiomer over the other is expressed...
11. Enantiopurity - How pure a substance is in one enantiomer over the other is expressed as a % enantiomeric excess. Consider the following theoretical scenario: CH2OH CH2OH optical rotation: +100° optical rotation: -100° % composition % enantiomeric excess observed rotation In the lab, a polarimeter can give you optical purity (% enantiomeric excess) by comparing against a pure enantiomeric standard: Optical purity = specific rotation of sample - X 100 specific rotation of pure enantiomer Page 2 A mixture...
ootical for pure substance is +40 1. As the new chemist working at "Drugs Us", you...
ootical for pure substance is +40
1. As the new chemist working at "Drugs Us", you are given the task of resolving racemic phenylethyl- amine into its individual enantiomers using (S)-malic acid as resolving agent. After you carried out the resolution, you labeled the products you isolated "Sample A" and "Sample B. You subjected both samples to polarimetry ( = 589 nm (sodium D-line), 1-dm cell) and obtained the following results. Sample A: 1.00 g dissolved in 10.0 mL methanol...
7a.) Enantiomerically pure xylose (shown below) has a specific rotation of approximately -21 Is t...
7a.) Enantiomerically pure xylose (shown below) has a specific rotation of approximately -21 Is the enantiome r shown below the D or the L form of xylose? How do you know? (3 points) e of xylose were made and it was found to have a specific rotation of-15°, what would be the enantiomeric excess of this sample (clearly show your working)? (3 points) What would be the stereoisomeric composition of the mixture (D/L)? (2 points) CHO но он HOH CH2OH...
9. Specific rotation of enantiopure (R)-malic acid is -6. An unknown sample was found to have a specific rotation of -2 Which isomer is the major component in the unknown mixture? HO OH Malic Acid O OH Circle one: R S What is the enantiomeric excess of the mixture? Show your calculations.
9. Specific rotation of enantiopure (R)-malic acid is -6. An unknown sample was found to have a specific rotation of -2 Which isomer is the major component in...
3. Pure Θ Kaylanoic acid has a specific rotation of-160° (same conditions and temperature as sample above). What is the % optical purity of the sample above ? (0.75 points) 4. 3.5 mg of optically-enriched(-) antibiotic Zachromycin was dissolved in 1.00 mL methanol in a 1.00 mL volumetric flask. The optical rotation was found to be -0.02220 in a 5.0 cm cell. What is the specific rotation? (0.75 points) 5. Calculate the enantiomeric excess and the specific rotation of a...
3. For the structure below determine the number of stereocenters. Determine the number of stereoisomers for the structure and draw all of them? Determine the enantiomers and which are diasteriomers. Determine the absolute configuration for both for both enantiomers. 10 pts 4. What would be the observed optical rotation of a sample of 3.2 R of pure (.) - 3-chloropentanoic acid with a specific rotation of 30.0 degrees in 100 ml of water, measured in 25 cm cuvette. 4 pts...
The specific rotation of pure (-)-2-butanol is -13.5°. If a mixture has a specific rotation of +7o, how much of each form (+ and-) is present and what is the e.e. of the mixture? 21. 22. (-)-Lactic acid has a specific rotation of -3.8°. What is the specific rotation of a solution containing 7.5 g of (--lactic acid and 2.5 g of (+)-lactic acid? 23. Draw the Fischer projection of (2R,4R)-2,4-dibromopentane. w? And draw the 24. How many diastereomers are...
optical activity problems.. please show all steps i dont
understand
You have a sample (Sample X) which is a mixture of +/- Carvone. The solution was made by dissolving 4.50 g of the sample in enough methanol to bring the volume of solution to 10,0 ml. Some of the solution is placed in a 100 cm polarimeter cell and its optical rotation is measured at 25°C using light of the sodium D line wavelength (589.6 nm). The observed rotation is...
7) A solution of an enantiomerically pure sample of (R)- 3-chloropentanoic acid is made by dissolving 2.5 g of the compound in 100 mL of water. a. Calculate the specific rotation of (R)- 3-chloropentanoic acid if the observed rotation of the above sample is +2.78° when measured in a 40 cm tube. g/mL +2.7% = 127.5 10025(4) b. What is the specific rotation of (S)-3-chloropentanoic acid? -27,8 c. A chemist prepares a sample which is a mixture of both enantiomers...
11. Enantiopurity - How pure a substance is in one enantiomer over the other is expressed as a % enantiomeric excess. Consider the following theoretical scenario: CH2OH CH2OH optical rotation: +100° optical rotation: -100° % composition % enantiomeric excess observed rotation In the lab, a polarimeter can give you optical purity (% enantiomeric excess) by comparing against a pure enantiomeric standard: Optical purity = specific rotation of sample - X 100 specific rotation of pure enantiomer Page 2 A mixture...
ootical for pure substance is +40
1. As the new chemist working at "Drugs Us", you are given the task of resolving racemic phenylethyl- amine into its individual enantiomers using (S)-malic acid as resolving agent. After you carried out the resolution, you labeled the products you isolated "Sample A" and "Sample B. You subjected both samples to polarimetry ( = 589 nm (sodium D-line), 1-dm cell) and obtained the following results. Sample A: 1.00 g dissolved in 10.0 mL methanol...
7a.) Enantiomerically pure xylose (shown below) has a specific rotation of approximately -21 Is the enantiome r shown below the D or the L form of xylose? How do you know? (3 points) e of xylose were made and it was found to have a specific rotation of-15°, what would be the enantiomeric excess of this sample (clearly show your working)? (3 points) What would be the stereoisomeric composition of the mixture (D/L)? (2 points) CHO но он HOH CH2OH...
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