Homework Answers
CH3OK is a base ,
which favours E2- elimination reaction. E2 elimination requires the
anti-periplanar arrangements of beta H and leaving group ( here Br)
as shown above. This process goes with single step manner forming a
transition state as shown in mechanism.
For any confusion feel free to ask.
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1. Predict the MAJOR product of the following reaction and state the mechanism that leads to...
Predict the major product for the following reaction. Label whether the reaction will proceed through an...
Predict the major product for the following reaction. Label whether the reaction will proceed through an SN2, Sn1, E2, or E1 mechanism. SN2 / S1/E2/E1 сн. Br NaCN (1 mol) (1 mol) Predict the major product for the following reaction. Label whether the reaction will proceed through an SN2, SN1, E2, or E1 mechanism. SN27 SN1/E2/E1 NaOCH; Сн,он Draw the line structures of the reactants below and predict the product of their reaction. Label the reaction as SN1, SN2, E1,...
1. A) Show each possible product for the reaction below and predict the major product. Be...
1. A) Show each possible product for the reaction below and predict the major product. Be sure. to include all geometric isomers. (1 pt) b Na B) Draw the rotamer that leads to the major product for the reaction above as a Newman projection. (1 pt) 2. Circle the substrates which can undergo elimination through the E2 mechanism. (Hint: substrates may not be drawn in the proper conformation for an E2 reaction). (0.5 pts) to x Kto 3. Circle the...
1. Predict whether the following reactions are likely to proceed by an E1 or E2 mechanism....
1. Predict whether the following reactions are likely to proceed
by an E1 or E2 mechanism. PLEASE show the mechanism and product of
the reaction!!!!
2. Explain each prediction.
Predicting mechanisms: E1 or E2? 1. Predict whether the following reactions are likely to proceed by an El or E2 mechanism. 2. Explain each prediction. Br co KOH H2O Br CH,CH,OH Br CH2CH OH CH,0/CH,OH Br
Question 13 Predict the major product for the following reaction and previde a curved arrow mechanism...
Question 13 Predict the major product for the following reaction and previde a curved arrow mechanism for the formation of the product он HBr correct Draw the product of the reacton H,C Br CH
6) Predict the major product in each of the following reactions and indicate if it came...
6) Predict the major product in each of the following reactions and indicate if it came from an Sn1, S2, E1, or E2 reaction. H3C Br NaOme CH3 H2O H Br MeOH 'BUOK H Br DMSO H3C Br NaOme CH3 H20 MeOH H OTS ЕКОН
(8 pts) For each reaction, predict what mechanism will account for the major product(s) formed and...
(8 pts) For each reaction, predict what mechanism will account for the major product(s) formed and write (SN1, SN2, E1, E2 or N.R.) in the boxes provided. Explanations or drawings are NOT required. 4. а. Н-о Br heat b. OTs NaOEt НOE с. NaCl OTs DMSO d. CI CHон
10. 26. Predict the major product and mechanism (E1, E2, SN1, or SN2): КОССH), acetone Br...
10. 26. Predict the major product and mechanism (E1, E2, SN1, or SN2): КОССH), acetone Br Predict the result of reacting НЕг ROOR НBr
For the following reaction, (a) predict the reaction pathway (SN2, E2, S1/E1) based on our predictive...
For the following reaction, (a) predict the reaction pathway (SN2, E2, S1/E1) based on our predictive model and (b) draw the product(s). ONa Provide the complete curved arrow mechanism for the rearrangement shown here. Hint: The first step makes the alcohol a better leaving group using a proton source. Complete the following sequence by filling in missing reagents or providing the product(s) of a reaction. Sequential steps, if necessary, should be numbered. OMs ОН minor product major product
Complete the curved arrow electron-pushing mechanism and predict the major organic product of the reaction when...
Complete the curved arrow electron-pushing mechanism and predict the major organic product of the reaction when 1-chloropentane is treated with hydroxide in ethanol as shown below. Use curved arrows to show the conversion to the product. Draw the structure of the organic product formed in the reaction. Draw lone pairs. Select the option that describes the mechanism of the reaction above. S_N1 S_N2 E1 E2
Complete the curved arrow electron-pushing mechanism and predict the major organic product of the reaction when...
Complete the curved arrow electron-pushing mechanism and predict the major organic product of the reaction when 1-chloropentane is treated with hydroxide in ethanol as shown below. Use curved arrows to show the conversion to the product. Draw the structure of the organic product formed in the reaction. Draw lone pairs. Select the option that describes the mechanism of the reaction above. S_N1 S_N2 E1 E2
Predict the major product for the following reaction. Label whether the reaction will proceed through an SN2, Sn1, E2, or E1 mechanism. SN2 / S1/E2/E1 сн. Br NaCN (1 mol) (1 mol) Predict the major product for the following reaction. Label whether the reaction will proceed through an SN2, SN1, E2, or E1 mechanism. SN27 SN1/E2/E1 NaOCH; Сн,он Draw the line structures of the reactants below and predict the product of their reaction. Label the reaction as SN1, SN2, E1,...
1. A) Show each possible product for the reaction below and predict the major product. Be sure. to include all geometric isomers. (1 pt) b Na B) Draw the rotamer that leads to the major product for the reaction above as a Newman projection. (1 pt) 2. Circle the substrates which can undergo elimination through the E2 mechanism. (Hint: substrates may not be drawn in the proper conformation for an E2 reaction). (0.5 pts) to x Kto 3. Circle the...
1. Predict whether the following reactions are likely to proceed
by an E1 or E2 mechanism. PLEASE show the mechanism and product of
the reaction!!!!
2. Explain each prediction.
Predicting mechanisms: E1 or E2? 1. Predict whether the following reactions are likely to proceed by an El or E2 mechanism. 2. Explain each prediction. Br co KOH H2O Br CH,CH,OH Br CH2CH OH CH,0/CH,OH Br
Question 13 Predict the major product for the following reaction and previde a curved arrow mechanism for the formation of the product он HBr correct Draw the product of the reacton H,C Br CH
6) Predict the major product in each of the following reactions and indicate if it came from an Sn1, S2, E1, or E2 reaction. H3C Br NaOme CH3 H2O H Br MeOH 'BUOK H Br DMSO H3C Br NaOme CH3 H20 MeOH H OTS ЕКОН
(8 pts) For each reaction, predict what mechanism will account for the major product(s) formed and write (SN1, SN2, E1, E2 or N.R.) in the boxes provided. Explanations or drawings are NOT required. 4. а. Н-о Br heat b. OTs NaOEt НOE с. NaCl OTs DMSO d. CI CHон
10. 26. Predict the major product and mechanism (E1, E2, SN1, or SN2): КОССH), acetone Br Predict the result of reacting НЕг ROOR НBr
For the following reaction, (a) predict the reaction pathway (SN2, E2, S1/E1) based on our predictive model and (b) draw the product(s). ONa Provide the complete curved arrow mechanism for the rearrangement shown here. Hint: The first step makes the alcohol a better leaving group using a proton source. Complete the following sequence by filling in missing reagents or providing the product(s) of a reaction. Sequential steps, if necessary, should be numbered. OMs ОН minor product major product
Complete the curved arrow electron-pushing mechanism and predict the major organic product of the reaction when 1-chloropentane is treated with hydroxide in ethanol as shown below. Use curved arrows to show the conversion to the product. Draw the structure of the organic product formed in the reaction. Draw lone pairs. Select the option that describes the mechanism of the reaction above. S_N1 S_N2 E1 E2
Complete the curved arrow electron-pushing mechanism and predict the major organic product of the reaction when 1-chloropentane is treated with hydroxide in ethanol as shown below. Use curved arrows to show the conversion to the product. Draw the structure of the organic product formed in the reaction. Draw lone pairs. Select the option that describes the mechanism of the reaction above. S_N1 S_N2 E1 E2
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