Complete the following reactions by writing major products or necessary reagents:
Reactions: Give the structure of the major product(s) or the reagents necessary to complete each of the following reactions. If necessary, indicate the product stereochemistry.
Complete the following reaction sequences by drawing the major
products or the reagents necessary to make them. Be sure to include
stereochemistry when appropriate.
1. (48 pts) Complete the following reaction sequences by drawing the major products or the reagents necessary to make them. Be sure to include stereochemistry when appropriate. HBr Benzene FeBr3 HO NaH DMF hv NaNH2 2 BnBr CH2Cl2 Benzene Br2 cat. H+ H2o Ph NaOH NBS H Br H20 hv
(30 pts) (a) Complete the following reactions by drawing the major products or the reagents to make them. (b) Label each reaction as Sy1.S2, El, E2, or addition. Be sure to 1. KOMe b. HOMe H20 d. MeOH cat. H Cl EtoH Cl
V. Reactions. Draw the major expected products or supply the necessary reagents for each of the following reactions. Be sure to indicate stereochemistry when relevant. (21) AICI 1.) KMnO4. OH 2.) H,09 FeBry 1. HNO2, H,SO + Mg, anh. ether 2. CO2 4. LIAIH, then H 1. CH3COCI 2. Bry/FeBry 3. NaOH, HO
(32 pts) Complete the following reaction sequences by drawing the major products or the reagents necessary to make them. Be sure to include stereochemistry when appropriate. 2. NaOEt 'Br DMF EtOH, Δ Br 2 Cl Cl Cl HO Br Cl Cl H2 (8) Lindlar's cat.
Complete the following reaction
sequences by drawing the major products or reagents needed to make
them.
2. (2 4 pts) Complete the following reaction sequences by drawing the major products or the reagents necessary to make them. Be sure to include stereochemistry when appropiate Br2 H20 Br HBr NaNH2 b. H202 m-CPBA c.
The instructions say: Complete the following reaction sequences
by drawing the major products or the reagents necessary to make
them. Be sure to include stereochemistry when appropriate.
reagents necessary to make them. Be sure to include stereochemistry when appropriate H2 (8) H2o Lindlar's cat Br 04 NaOEt b. CH2Cl2 DMSO NaNH Br NaOEt d. EtOH Br2 KOr-Bu MeOH HOr-Bu OH H2 (g) Pd /C
Provide the reagents necessary to complete the following
reactions. More than one step may be necessary, if so number
separate steps.
ОН 앳 ОН НО 옛 он Br НО. + en НО, HO + en
3. Provide the reagents necessary to carry out the following reactions or provide the starting materials or major products of the following reactions, Indicate racemic mixtures where necessary. (39 pts) 1)AIC осн, a. Ph 2) PaC H Н,со 45 1) HS0, HNO b. 2) Pd/c. H Н,со он c. Ph HO, он