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1-One-half of an electrochemical cell consists of a pure Zinc electrode in a solution of Zn2+...

1-One-half of an electrochemical cell consists of a pure Zinc electrode in a solution of Zn2+ ions; the other half is a Lead electrode immersed in a solution of Pb2+ solution. The half-cell potentials for Zinc and Lead are -0.763 V and -0.126 V, respectively.

(a) If the cell is a standard one, write the spontaneous overall reaction and calculate the voltage that is generated.

(b) Compute the cell potential at 25oC if the Zn2+ and Pb2+ concentrations are 10-2 M and 10-4 M, respectively. Is the spontaneous reaction direction still the same as for the standard cell?

The room-temperature electrical conductivity of a silicon specimen is 1000 (Ω-m)-1. The electron concentration is known to be 8.87 x 1021 electron m-3. Assuming the electron and hole mobility values are 0.14 m2/V. s and 0.05 m2/V. s, respectively. Note that the density of the silicon is 2.33 g/cm3 and its atomic mass is 28.09 g/mol. The electron charge is 1.6 x 10-19 C and Avogadro’s number = 6.023 x 1023 atoms/mol. Answer the following questions: (a) Compute the hole concentration. (b) Calculate the number of free electron per atoms. (c) Is the specimen n-type extrinsic, or p-type extrinsic? Why?2-

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