C. REACTIONS: (8 points each; 40 points total) For each of the following reactions or series...
match the right reagent 3 OH + enantiomer + enantiomer 5 CO A.) PBrs B.) NBS, hv C.) D.) NaOH E.) NaNH2 F.) Br2 G.) HCI H.) Cl2, H2O 1.) HBO J.) H2 (1 eq), Pt K.) Na, NH3 L.) H2SO4, H20 M.)1. Hg(OAC)2 0.) N.) 1. mCPBA 2. H+, H2O 2. NaBH4 P.) 1. BH3 2. H2O2, NaOH 3 OH + enantiomer + enantiomer 6 CO A.) PBrs B.) NBS, hv C.) D.) NaOH E.) NaNH2 F.) Br2 G.)...
match the right reagent ОН 7 8 ОН г. . . . . . . + enantiomer A.) PBrs B.) NBS, hv C.) D.) NaOH E.) NaNH2 F.) Br2 G.) HCI H.) Cl2, H2O 1.) HBO J.) H2 (1 eq), Pt K.) Na, NH3 L.) H2SO4, H20 M.)1. Hg(OAC)2 0.) N.) 1. mCPBA 2. H+, H2O 2. NaBH4 P.) 1. BH3 2. H2O2, NaOH
Question 13 24 pts Match each reaction with its reagents. HO CI N + enantiomer A.) PBr3 B.) NBS, hv C.) D.) NaOH E.) NaNH2 F.) Br2 G.) HCI H.) Cl2, H2O 1.) HBO J.) H2 (1 eq), Pt K.) Na, NH3 L.) H2SO4, H2O M.)1. Hg(OAC)2 2. NaBH4 0.) N.) 1. mCPBA 2. H+, H2O P.) 1. BH3 2. H2O2, NaOH
Match each reaction with its reagents. HO 1 + enantiomer 3 OH + onantiomer + enantiomer 5 السر OH 사 Ñ 8 OH ot но. 10 Br + enantiomer Br n 11 Br 12 Reagents: A.) PBS B.) NBS, hv C.) D) NaOH E.) NaNH2 F.) Br2 G.) HCI H.) Cl2, H2O I.) HBO J.) H2 (1 eq), Pt K)Na, NH3 L.) H2SO4, H2O 0.) M.)1. Hg(OAc)2 2. NaBH4 N.) 1. mCPBA 2. H+, H20 P.) 1. BHE 2. H2O2,...
Match each reaction with its reagents. HO 2 + enantiomer 3 ОН 4 + enantiomer + enantiomer 5 لح 6 OH 7 8 OH 9 to C НО. 10 Br + enantiomer Br 11 Br 12 red lockdown Reagents: A.) PB B.) NBS, hv D) NaOH E.) NaNH2 F.) Bra G.) HCI H.) Cl2, H2O 1.) HBO J.) H2 (1 eq), Pt K) Na, NH3 L.) H2SO4, H2O 0.) M.)1. Hg(OAc)2 2. NaBH4 N.) 1. mCPBA 2. H+, H2O P.)...
23Dime PROTON 8. (4 points each) Complete the following two reactions, No2 reduction 1) LIATH, (excess) 2) H,09 (Major Organic Product) 9. (5 points) Complete the following reaction. Compare the stability of the organic starting material with the major organic product. Discuss the driving force(s) of this reaction. me ph howet v ph" 1. NaOH, HO NH2 2.HCI, H20 PN h
3. Complete each of the following reactions. Draw the structure of the organic product or products in the space provided. Show stereochemistry if appropriate. (3 points each) SN2 reaction (a) (CH3)CHCH2Cl + NaCN Sn1 reaction (b) (CH3)CHCH,CI + NaCN (C) M Sn2 reaction ¢l + NaOH - ACH. E1 reaction (d) (CH3)3CCH,OH + HCI major product Ez reaction Cl + NaOH - LCH3 н Ereaction Cl + H20
2. Draw the major product for the following reactions. 6.Draw the final product for the following reactions 2. Draw the major product for the following reactions. 1) TCI 2) NaOEL, Heat 3) 0 4) DMS 1) NBS, heat (1 eq.) 2) NaNH, DMS0 3) KMnO4 (aq) NaOH, cold 4) NaCl acetic acid 1) , 2) H.O 3)Ni, 1, 150, 100 atm 1) R RH 2) H.O., NaOH 3) NBS, heat (I eq) 1) KMnO heat 2) Na, NH, CH,OH 3)...
What is the correct sequence of reactions that can achieve the following multistep transformation? List in the correct order. (No spaces nor commas in between letters) eg: GAKJO ☺ > REAGENTS A Br2 B TosCl, pyr CHOH SO, cat DO Na 1 MeBr 2. EtBr 3. NaNH 1 eq E 1. OsO4 2. NaHSO3 F NaNHExcess GHO H NBS, hv I HBr ROOR L HBr M NaOtBu N NaOEt O NaoMe PETOH, H+ Cat Q NaCN RH, Lindlar's SH, Pt...
What is the correct sequence of reactions that can achieve the following multistep transformation? 19:59 TM SM SH REAGENTS A Br B Br HO C H2O HSO4 cat D 1. MCPBA 2.H,0 El. OsO4 2. NaHso F NaNH2 Excess G HO H NBS, hv I HBr ROOR L HBr M NaOtBu N NaOEt O NaOMe P EtOH, H Cat Q Li NH liq RHa Lindlar's S H, Pt TLO 2DMS U1O 2.H20 V Br hv W1. BH,/THF 2NaOH, H20 X1....