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rojection Formulas for each model in #16 (again orient the carbon chain up and down). Are...
19-26 thanks! 19-29* PART 3: 2,3-BUTANEDIOL CH-CH(OH)-CH(OH)-CH, mirror images, not superimposable Build as many models of...
19-26 thanks!
19-29*
PART 3: 2,3-BUTANEDIOL CH-CH(OH)-CH(OH)-CH, mirror images, not superimposable Build as many models of 2,3-butanediol as you can. First, attach two carbons with a single bond. To each carbon add one carbon, one hydrogen, and one oxygen. To complete the structure, Ti the remaining hydrogen atoms. Remember, a model is not different if it is completely superimposable on one already constructed! 13. How many stereochemically different models are possible for 2,3-butanediol? 14. What characteristic does one of these...
CHCH(OH)-CH(OH)-CH3 PART 3: 23-BUTANEDIOL Build as many models of 2.3-butanediol as you can. First, attach two...
CHCH(OH)-CH(OH)-CH3 PART 3: 23-BUTANEDIOL Build as many models of 2.3-butanediol as you can. First, attach two carbons with a single bond To each carbon add one carbon, one hydrogen, and one oxygen. To complete the structure. fill in the remaining hydrogen atoms. Remember, a model is not different if it is completelv superimposable on one already constructed! 13. How many stereochemically different models are possible for 2.3-butanediol? 14. What characteristic does one of these models have that makes it different?...
1. Construct a model that has a central carbon atom with 4 different colored spheres attached...
1. Construct a model that has a central carbon atom with 4 different colored spheres attached to it, representing four different atoms or groups. Draw a solid/dashed-wedge structure of this model here and answer the following questions. C (a blue ball) D Fig. 1 B 2. Reconstruct the original stereogenic carbon with the four different colored balls again. Set the model on the table so that the blue ball (C In the Fig 1) points upwards. a. Looking down on...
3. Diastereomers and Meso Forms. When a molecule has two or more stereogenic centers, stereoisomers that...
3. Diastereomers and Meso Forms. When a molecule has two or more stereogenic centers, stereoisomers that are not mirror images can exist; these are called diastereoisomers. Within this general class, there are special types of stereoisomers that are always optically inactive and are called meso forms. Construct a model with four different colored balls about a carbon center. Construct another identical to the first and verify this by the superimposition test. Now remove the same colored balls, blue (C from...
3. Diastereomers and Meso Forms. When a molecule has two or more stereogenic centers, stereoisomers that...
3. Diastereomers and Meso Forms. When a molecule has two or more stereogenic centers, stereoisomers that are not mirror images can exist; these are called diastereoisomers. Within this general class, there are special types of stereoisomers that are always optically inactive and are called meso forms. Construct a model with four different colored balls about a carbon center. Construct another identical to the first and verify this by the superimposition test. Now remove the same colored balls, blue (C from...
1. Construct a model of the 2,3-dibromopentane isomer and label the chiral centers as R or S. The...
1. Construct a model of the 2,3-dibromopentane isomer and label the chiral centers as R or S. Then make a model of its mirror image and draw it below, again labeling the chiral centers as R or S. a. Convert both models to their most stable conformation and draw their Newman projections looking down the center bond. b. On one model interchange the H and Br on one of the chiral centers. How is this molecule related to the other...
A. Enantiomers: Certain substances have the unique property of rotating the plane of plane-polarized light. Such...
A. Enantiomers: Certain substances have the unique property of rotating the plane of plane-polarized light. Such light rotation is detectable with the aid of a polarimeter. In order for a molecule to be optically active it must be chiral. Chiral objects lack a plane of symmetry and are non-superimposable on their mirror images. A sp?- hybridized carbon atom can fulfill these requirements if all four of its substituents are different. 1. Methane a) Prepare a methane molecule and then substitute...
3. Cyclic compounds The presence of the ring in all but very large ring cyclic molecules...
3. Cyclic compounds The presence of the ring in all but very large ring cyclic molecules prevents full rotation of the ring atoms. For this reason, stereoisomerism may also occur in cyclic molecules. a) Prepare a model of cyclohexane, C6H12. Draw the condensed formula. b) Build a model of methylcyclohexane (C7H14) by replacing one of the hydrogens of cyclohexane with a methyl group. Draw the skeletal formula for methylcyclohexane. 2 c) How many different isomers exist for methylcyclohexane (CyH34)? d)...
Week 10- Constitutional isomers Constitutional isomers have the same molecular formula, but their atoms are bonded...
Week 10- Constitutional isomers Constitutional isomers have the same molecular formula, but their atoms are bonded in different orders. These may be further distinguished as chain isomers, which differ only in hydrocarbon chain structure, positional isomers, which differ in the location of a functional group, and functional group isomers which differ in the nature of their functional groups. Typically chain and position isomers show only modest differences in their physical and chemical properties, while functional group isomers differ greatly from...
Questions 7-15 The molecule is ethane 71 2 O ACTIVITY 1.2.1 Biological Macromolecules in 3-D 7....
Questions 7-15 The molecule is ethane
71 2 O ACTIVITY 1.2.1 Biological Macromolecules in 3-D 7. Orient the two molecules so that portions of the mo lecules that would normally form intermolecular bonds lie next to each other. In this activity, you will build molecular models of biologically important molecules using ball-and-spring molecular model 1) What intermolecular forces help to hold these mo- building kits and then you will view these and other molecules lecules together! of interest using computer-generated...
19-26 thanks!
19-29*
PART 3: 2,3-BUTANEDIOL CH-CH(OH)-CH(OH)-CH, mirror images, not superimposable Build as many models of 2,3-butanediol as you can. First, attach two carbons with a single bond. To each carbon add one carbon, one hydrogen, and one oxygen. To complete the structure, Ti the remaining hydrogen atoms. Remember, a model is not different if it is completely superimposable on one already constructed! 13. How many stereochemically different models are possible for 2,3-butanediol? 14. What characteristic does one of these...
CHCH(OH)-CH(OH)-CH3 PART 3: 23-BUTANEDIOL Build as many models of 2.3-butanediol as you can. First, attach two carbons with a single bond To each carbon add one carbon, one hydrogen, and one oxygen. To complete the structure. fill in the remaining hydrogen atoms. Remember, a model is not different if it is completelv superimposable on one already constructed! 13. How many stereochemically different models are possible for 2.3-butanediol? 14. What characteristic does one of these models have that makes it different?...
1. Construct a model that has a central carbon atom with 4 different colored spheres attached to it, representing four different atoms or groups. Draw a solid/dashed-wedge structure of this model here and answer the following questions. C (a blue ball) D Fig. 1 B 2. Reconstruct the original stereogenic carbon with the four different colored balls again. Set the model on the table so that the blue ball (C In the Fig 1) points upwards. a. Looking down on...
3. Diastereomers and Meso Forms. When a molecule has two or more stereogenic centers, stereoisomers that are not mirror images can exist; these are called diastereoisomers. Within this general class, there are special types of stereoisomers that are always optically inactive and are called meso forms. Construct a model with four different colored balls about a carbon center. Construct another identical to the first and verify this by the superimposition test. Now remove the same colored balls, blue (C from...
3. Diastereomers and Meso Forms. When a molecule has two or more stereogenic centers, stereoisomers that are not mirror images can exist; these are called diastereoisomers. Within this general class, there are special types of stereoisomers that are always optically inactive and are called meso forms. Construct a model with four different colored balls about a carbon center. Construct another identical to the first and verify this by the superimposition test. Now remove the same colored balls, blue (C from...
A. Enantiomers: Certain substances have the unique property of rotating the plane of plane-polarized light. Such light rotation is detectable with the aid of a polarimeter. In order for a molecule to be optically active it must be chiral. Chiral objects lack a plane of symmetry and are non-superimposable on their mirror images. A sp?- hybridized carbon atom can fulfill these requirements if all four of its substituents are different. 1. Methane a) Prepare a methane molecule and then substitute...
3. Cyclic compounds The presence of the ring in all but very large ring cyclic molecules prevents full rotation of the ring atoms. For this reason, stereoisomerism may also occur in cyclic molecules. a) Prepare a model of cyclohexane, C6H12. Draw the condensed formula. b) Build a model of methylcyclohexane (C7H14) by replacing one of the hydrogens of cyclohexane with a methyl group. Draw the skeletal formula for methylcyclohexane. 2 c) How many different isomers exist for methylcyclohexane (CyH34)? d)...
Week 10- Constitutional isomers Constitutional isomers have the same molecular formula, but their atoms are bonded in different orders. These may be further distinguished as chain isomers, which differ only in hydrocarbon chain structure, positional isomers, which differ in the location of a functional group, and functional group isomers which differ in the nature of their functional groups. Typically chain and position isomers show only modest differences in their physical and chemical properties, while functional group isomers differ greatly from...
Questions 7-15 The molecule is ethane
71 2 O ACTIVITY 1.2.1 Biological Macromolecules in 3-D 7. Orient the two molecules so that portions of the mo lecules that would normally form intermolecular bonds lie next to each other. In this activity, you will build molecular models of biologically important molecules using ball-and-spring molecular model 1) What intermolecular forces help to hold these mo- building kits and then you will view these and other molecules lecules together! of interest using computer-generated...
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