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Why is equatorial methylcyclohexane more stable than axial methylcyclohexane? 2.32
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Answer #1

Equitorial methylcyclohexane and axial methylcyclohexane are diastereomers.

Diastereomers have difference in energies so, obviously one form is more stable than the other.

In axial methylcyclohexane, vanderwals forces of interaction between one of the methyl hydrogens and axial hydrogen atoms of the carbon ring destabilise the structure.

So equitorial methylcyclohexane is more stable than the axial methyl cyclohexane.

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