Oxidative additionHomework Answers
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Oxidative addition
Class Practice H3C. CH3 CH COOOH CH COOOH cold, dilute KMnoa oll Hizo or...
(2) NaBH4 (2) H202 OH cold, dilute KMnO4 "ОН H,C H,C HCO,H H,O с-с CH CH2CH,...
(2) NaBH4 (2) H202 OH cold, dilute KMnO4 "ОН H,C H,C HCO,H H,O с-с CH CH2CH, CH,CH2CH Predict the major products of the following reactions, including stereochemistry where appropriate. (a) (R)-2-butanol + TsCl in pyridine c) cyclooctanol + CrO3/H2SO4 (e) cyclopentylmethanol + Na2Cr 01/H2SO4 (g) n-butanol + HBr (i) potassium t-butoxide + methyl iodide (k) cyclopentanol + H2SO4/heat (m) sodium ethoxide +1-bromobutane (b) (S)-2-butyl tosylate +NaBr (d) cyclopentylmethanol + CrOs pyridine HC cyclopentanol + HCI/ZnCl2 (h) cyclooctylmethanol + CH3CH2MgBr (G)...
answer the following practice questions C(CH₃), CI - OCH₂CH3 - Br CH₂ CH2 -OCHS, C(CH), Cl...
answer the following practice questions
C(CH₃), CI - OCH₂CH3 - Br CH₂ CH2 -OCHS, C(CH), Cl H23,22°C CHSCH (CH)CI Ochela O (H3 ③ CH₂ - OH H2SO4 CH₃ H2O 0 CH2CH(CH) CH404 Hour tout ② H-C=C-H 24 25 16H₃ THE 2) H2O2, OH CH3 HgOnc, H2O DH 2-OH, NOBH4 KMnO4 OH, H2O CHEC-CIH - An @ KM, 04, cold 12 C=CH OH, H₂O
Name the following organic compounds. Please explain. ÇHz—CH CH3-CH-CH2 - CH2 - CH2-OH H3C- N- CH3...
Name the following organic compounds. Please explain.
ÇHz—CH CH3-CH-CH2 - CH2 - CH2-OH H3C- N- CH3 CH3 17. CH2-CH-CH2-CH2-O-CHZ CH2-O-CH3 CH3 18. 19. CH3 CH3 CH2 - CH-CH-C- CH2 CH2 - CH - CH2 - CH2-C-H CH CH3 Pongracando con 20. CH3 -CH-CH2-CH-C-OH 21. CH, -CH-C-CH=CH2 CHZ CHE 22. CH3-CH - CH2 - CH2 - C -0 - CH3 23. CH3-CH2—6- NH-CH3 CH CH CI CH2 - CH2 25. CH2 - CH3 CH2 - CH3 HO 27. ÇH2CH-CH2 ӧн Онон
Practice Set-lll CH3 o 1. H3c-C- CHa a HaC, CH3 PY ? H-C-N H Нас + OH T CH2 2. ? CH2 he N(CH3)2 O2N HaC CH3 Phosgen...
Practice Set-lll CH3 o 1. H3c-C- CHa a HaC, CH3 PY ? H-C-N H Нас + OH T CH2 2. ? CH2 he N(CH3)2 O2N HaC CH3 Phosgene, ? (Review a 3. O-CC2 2 CO2H PY ? HaC 4. Нас OH +CH3 NH2 ? H + excess CH30H ? 6. CH(CH2)16 heat b-(CH2)1CH3 heat ? 7. CaHs-C O-CH2 + NH2-OH hydrorylarnine O-
Practice Set-lll CH3 o 1. H3c-C- CHa a HaC, CH3 PY ? H-C-N H Нас + OH T...
RE klon 1 1 pt CH3 CH3 H₂O - H30* + cm ution 2 stion 3 stion 4 pt 18 1 pt H3C-¢-CI CH3 H3C---OH CH3 estion 5 1 pt 2...
RE klon 1 1 pt CH3 CH3 H₂O - H30* + cm ution 2 stion 3 stion 4 pt 18 1 pt H3C-¢-CI CH3 H3C---OH CH3 estion 5 1 pt 2-chloro-2-methylpropane reacts with water in three steps to yield 2-methylpropan-2-ol. One of these steps is shown below, add curved arrows to the mechanism to indicate the movement of electrons in this step. estion 6 1pt Arrow-pushing Instructions Question 7 1 pt Question 8 Question Question 10 1 pt pt pe...
146 ChemActivity 10: Oxidation and Reduction Model 8: Stereoselective Oxidative Cleavage of a x Bond Synthetic...
146 ChemActivity 10: Oxidation and Reduction Model 8: Stereoselective Oxidative Cleavage of a x Bond Synthetic Transformation 10.9: Syn Addition of Two OH Groups to ax Bond H OH но OsO4 or OH NaHSO a cold, dilute KMnO, solution, followed by KOH can be used in place of the highly toxic OsO Review of Synthetic Transformations 9.3/9.4 H HOHO OH acide ring opening eр МCРВА or 1) Кон. 2) neutrize with dilute acid basic ring opening он Critical Thinking Question...
answer the problem show work thanks CH3 H2O + 1. H-C-CH-CH-CH2 CH3 CH C 2, CHy-CH2-CH-CHOHPCC...
answer the problem show work thanks
CH3 H2O + 1. H-C-CH-CH-CH2 CH3 CH C 2, CHy-CH2-CH-CHOHPCC 25°C 50-55°C + HNO H2SO4 он H2CrO4 CH,CHCH acetone, 35°c Et O 2150113H20 5. CH3(CH2)2MgBr+ CH3(CH2)sC(CH2)sCH3 Nall CH2-CHCH2l H2SO4 140°C 6. CH3CH2CH2OH 7. CHCH CHOH 1) LiAIH(O-t-Bu)3,-78°C 2) H20 8. CH,C-CI HBr 9. CH2 CH-CH-CH2 40°C 10. H3C CIH2 Benzene 100℃ H3C 1. LiAIH/Et2O 11. CH,CH2CH,COH 2. H,0 12. + CH,CH,cCI AIC Benzene, 80°C 13. Br2 heat CH3 AlcI 15. 25°C conc. H2SO4 NaBH4...
Part A Choose the reagents that would be required to carry out the following synthesis: CH...
Part A Choose the reagents that would be required to carry out the following synthesis: CH 2 OH он H20, H+ O 1 . BH3; 2. HO, H202, H2O 03 followed by (CH3) 2S KMnO4, HO (warm, concd.) KMnO4, HO (cold, dilute) Submit Request Answer
2 problems REVIEW Topics [References) CH HC OCH Br2 CH3 B H3C CH,OH H₂C CH₂ Electrophilic...
2 problems
REVIEW Topics [References) CH HC OCH Br2 CH3 B H3C CH,OH H₂C CH₂ Electrophilic addition of hypohalous acids to alkenes yields a 1,2-haloalcohol called a halohydrin. Halohydrin formation, however, does not result from the addition of HOBr, for example. Instead the addition is done indirectly by reaction of the alkene with Br, in the presence of water. The reaction also works with Cl2 to give chlorohydrins instead of bromohydrins. The reaction proceeds through a cyclic intermediate known as...
g) Which structure is Z-2-bromo-3-methyl-2-pentene? CH3 H3C CH2CH3 H C=C CH-CH,CH, CH3 CH3 Вісн. C=C CH3...
g) Which structure is Z-2-bromo-3-methyl-2-pentene? CH3 H3C CH2CH3 H C=C CH-CH,CH, CH3 CH3 Вісн. C=C CH3 Br н Br | BÁ CHẠCH, C=C CH, CHỊCH, 10) Which compounds contain stereocenters? D) 1-chloropentane II) 2-chloropentane III) 3-chloropentane IV) 1,2-dichloropentane 11) Aspartame is an artificial, non-saccharide sweetener. It is made from two amino acids phenylalanine (methyl ester) and aspartic acid. Both aminoacids have one stercocenter. Both stereocenters have S-stereoconfiguration. Which of the two structures is aspartame? H2N-C-C-N-C-0-0 CH2 CH2 c=0 HO HO...
(2) NaBH4 (2) H202 OH cold, dilute KMnO4 "ОН H,C H,C HCO,H H,O с-с CH CH2CH, CH,CH2CH Predict the major products of the following reactions, including stereochemistry where appropriate. (a) (R)-2-butanol + TsCl in pyridine c) cyclooctanol + CrO3/H2SO4 (e) cyclopentylmethanol + Na2Cr 01/H2SO4 (g) n-butanol + HBr (i) potassium t-butoxide + methyl iodide (k) cyclopentanol + H2SO4/heat (m) sodium ethoxide +1-bromobutane (b) (S)-2-butyl tosylate +NaBr (d) cyclopentylmethanol + CrOs pyridine HC cyclopentanol + HCI/ZnCl2 (h) cyclooctylmethanol + CH3CH2MgBr (G)...
answer the following practice questions
C(CH₃), CI - OCH₂CH3 - Br CH₂ CH2 -OCHS, C(CH), Cl H23,22°C CHSCH (CH)CI Ochela O (H3 ③ CH₂ - OH H2SO4 CH₃ H2O 0 CH2CH(CH) CH404 Hour tout ② H-C=C-H 24 25 16H₃ THE 2) H2O2, OH CH3 HgOnc, H2O DH 2-OH, NOBH4 KMnO4 OH, H2O CHEC-CIH - An @ KM, 04, cold 12 C=CH OH, H₂O
Name the following organic compounds. Please explain.
ÇHz—CH CH3-CH-CH2 - CH2 - CH2-OH H3C- N- CH3 CH3 17. CH2-CH-CH2-CH2-O-CHZ CH2-O-CH3 CH3 18. 19. CH3 CH3 CH2 - CH-CH-C- CH2 CH2 - CH - CH2 - CH2-C-H CH CH3 Pongracando con 20. CH3 -CH-CH2-CH-C-OH 21. CH, -CH-C-CH=CH2 CHZ CHE 22. CH3-CH - CH2 - CH2 - C -0 - CH3 23. CH3-CH2—6- NH-CH3 CH CH CI CH2 - CH2 25. CH2 - CH3 CH2 - CH3 HO 27. ÇH2CH-CH2 ӧн Онон
Practice Set-lll CH3 o 1. H3c-C- CHa a HaC, CH3 PY ? H-C-N H Нас + OH T CH2 2. ? CH2 he N(CH3)2 O2N HaC CH3 Phosgene, ? (Review a 3. O-CC2 2 CO2H PY ? HaC 4. Нас OH +CH3 NH2 ? H + excess CH30H ? 6. CH(CH2)16 heat b-(CH2)1CH3 heat ? 7. CaHs-C O-CH2 + NH2-OH hydrorylarnine O-
Practice Set-lll CH3 o 1. H3c-C- CHa a HaC, CH3 PY ? H-C-N H Нас + OH T...
RE klon 1 1 pt CH3 CH3 H₂O - H30* + cm ution 2 stion 3 stion 4 pt 18 1 pt H3C-¢-CI CH3 H3C---OH CH3 estion 5 1 pt 2-chloro-2-methylpropane reacts with water in three steps to yield 2-methylpropan-2-ol. One of these steps is shown below, add curved arrows to the mechanism to indicate the movement of electrons in this step. estion 6 1pt Arrow-pushing Instructions Question 7 1 pt Question 8 Question Question 10 1 pt pt pe...
146 ChemActivity 10: Oxidation and Reduction Model 8: Stereoselective Oxidative Cleavage of a x Bond Synthetic Transformation 10.9: Syn Addition of Two OH Groups to ax Bond H OH но OsO4 or OH NaHSO a cold, dilute KMnO, solution, followed by KOH can be used in place of the highly toxic OsO Review of Synthetic Transformations 9.3/9.4 H HOHO OH acide ring opening eр МCРВА or 1) Кон. 2) neutrize with dilute acid basic ring opening он Critical Thinking Question...
answer the problem show work thanks
CH3 H2O + 1. H-C-CH-CH-CH2 CH3 CH C 2, CHy-CH2-CH-CHOHPCC 25°C 50-55°C + HNO H2SO4 он H2CrO4 CH,CHCH acetone, 35°c Et O 2150113H20 5. CH3(CH2)2MgBr+ CH3(CH2)sC(CH2)sCH3 Nall CH2-CHCH2l H2SO4 140°C 6. CH3CH2CH2OH 7. CHCH CHOH 1) LiAIH(O-t-Bu)3,-78°C 2) H20 8. CH,C-CI HBr 9. CH2 CH-CH-CH2 40°C 10. H3C CIH2 Benzene 100℃ H3C 1. LiAIH/Et2O 11. CH,CH2CH,COH 2. H,0 12. + CH,CH,cCI AIC Benzene, 80°C 13. Br2 heat CH3 AlcI 15. 25°C conc. H2SO4 NaBH4...
Part A Choose the reagents that would be required to carry out the following synthesis: CH 2 OH он H20, H+ O 1 . BH3; 2. HO, H202, H2O 03 followed by (CH3) 2S KMnO4, HO (warm, concd.) KMnO4, HO (cold, dilute) Submit Request Answer
2 problems
REVIEW Topics [References) CH HC OCH Br2 CH3 B H3C CH,OH H₂C CH₂ Electrophilic addition of hypohalous acids to alkenes yields a 1,2-haloalcohol called a halohydrin. Halohydrin formation, however, does not result from the addition of HOBr, for example. Instead the addition is done indirectly by reaction of the alkene with Br, in the presence of water. The reaction also works with Cl2 to give chlorohydrins instead of bromohydrins. The reaction proceeds through a cyclic intermediate known as...
g) Which structure is Z-2-bromo-3-methyl-2-pentene? CH3 H3C CH2CH3 H C=C CH-CH,CH, CH3 CH3 Вісн. C=C CH3 Br н Br | BÁ CHẠCH, C=C CH, CHỊCH, 10) Which compounds contain stereocenters? D) 1-chloropentane II) 2-chloropentane III) 3-chloropentane IV) 1,2-dichloropentane 11) Aspartame is an artificial, non-saccharide sweetener. It is made from two amino acids phenylalanine (methyl ester) and aspartic acid. Both aminoacids have one stercocenter. Both stereocenters have S-stereoconfiguration. Which of the two structures is aspartame? H2N-C-C-N-C-0-0 CH2 CH2 c=0 HO HO...
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