6-2
The conductivity of a cup of saturated AgCl solution is 0.0019 S.cm-1. What is the value of the solubility product constant of AgCl under the temperature and pressure of the day?
AgCl(s) → Ag+(aq) + Cl-(aq), Ksp = [Ag+][Cl-]
Thank you so much.
6-2 The conductivity of a cup of saturated AgCl solution is 0.0019 S.cm-1. What is the...
Silver chloride, AgCl, is a sparingly soluble solid. Answer the following questions about a saturated solution prepared by placing solid silver chloride in a 1.94 x 10-5 M NaCl(aq) solution. At some temperature, the silver ion concentration, [Ag+], was found to be 6.24 x 10-6 M. (a) What is the concentration of chloride ions, [CI – ], in the resulting solution? XM (b) What is the molar solubility of silver chloride, AgCl, in 1.94 x 10-5 M NaCl? 4.9 6.24e-6...
AgCl (s) + --> <-- Ag + (aq) + Cl- (aq) Shown above is information about the dissolution of AgCl in water at 298 K. In a chemistry lab a student wants to determine the value of s, the molar solubility of AgCl, by measuring [Ag+] in a saturated solution prepared by mixing excess AgCl and distilled water. How would the results of the experiment be altered if the student mixed excess AgCl with tap water (in which [Cl-] =...
A saturated solution of calcium iodate contains 2.37 g/L of Ca(IO3)2. (a) What is the solubility of calcium iodate in mol/L? (b) What are the concentrations of Ca2+ and IO3 – ion, respectively, in the saturated solution? (c) Calculate the Ksp value for Ca(IO3)2. Part b ) Silver ion, Ag+ , readily forms complex ion, Ag(S2O3)2 3– , with thiosulfate, S2O3 2– , according to the following equation: Ag+ (aq) + 2S2O3 2– (aq) ⇌ Ag(S2O3)2 3– (aq); Kf =...
What is the solubility of AgCl in pure water at 25°C? The Ksp of AgCl is 1.8x10^-10. 9.0 x 10^-11 1.3 x 10^-5 1.8 x 10^-3 3.6 x 10^-10 What is the solubility of AgCl in 10 M NH3? The Kf of Ag(NH3)2+ from AgCl(s) in aqueous NH3 is 0.0031, which is for the balanced reaction shown below. AgCl(s) + 2 NH3(aq) → Ag(NH3)2+(aq) + Cl-(aq) Kf = 0.0031 0.176 M 0.426 M 0.023 M 0.557 M
Consider the Gibbs energies at 25 ∘C. SubstanceSubstance ΔG∘f (kJ⋅mol−1)ΔGf∘ (kJ·mol−1) Ag+(aq)Ag+(aq) 77.177.1 Cl−(aq)Cl−(aq) −131.2−131.2 AgCl(s)AgCl(s) −109.8−109.8 Br−(aq)Br−(aq) −104.0−104.0 AgBr(s)AgBr(s) −96.9−96.9 (a) Calculate ΔG∘rxn for the dissolution of AgCl(s)AgCl(s). kJ⋅mol−1 (b) Calculate the solubility-product constant of AgCl. K= (c) Calculate ΔG∘rxnΔGrxn∘ for the dissolution of AgBr(s)AgBr(s). kJ⋅mol−1kJ⋅mol−1 (d) Calculate the solubility-product constant of AgBr. K=K=
The solubility product of reaction below at 25C is 1.6x10^-10: AgCl(s) <-> Ag+(aq) + Cl-(aq) show work please and thank you!
A12a The cell Ag //AgCl (sat’d), KCl (1.00 M) //NiL2 (0.0250 M), NaL (0.150 M) //Ni has a voltage of -0.767 V. What is the overall formation constant of NiL2? Given: AgCl(s) + e Ag(s) + Cl- Eo = +0.222 V Ni2+ + 2e Ni(s) Eo = -0.257 V A12b Consider the following standard reduction potential: Ag+ + e Ag(s) Eo = +0.800 V AgI(s) + e Ag(s) + I- Eo = -0.164 V Calculate the solubility constant, Ksp at...
The value of the equilibrium constant for the following chemical equation is Kc = 5.2 ×103 AgCl (s) + 2S2O32-<-->[Ag(S2O3)2]3- (aq) + Cl– (aq) Calculate the solubility of AgCl (s) in an aqueous solution whose equilibrium concentration of S2O32- is 0.015 M. Ksp = 1.8 × 10-10 M2 for AgCl
5. Based on the AGⓇ =-RT In K expression, would you predict that AgCl(s) dissolving into Ag+ (aq) + CI+ (aq) [Ksp = 1.8x10-1') is a spontaneous process? Would you expect Co3+ (aq) +6NH3(aq) forming the [CO(NH3)6]+ complex ion [Kp = 4.5x1033] to be a spontaneous process? How does the magnitude of the equi- librium constant relate to the AGº? If a saturated solution of calcium hydroxide is prepared and its Ksp is determined, how can the AG = AGº+RT...
#9 and #10 Thank you solubility of the slightly soluble salt The solubility of AgCl is the same in a 1.0 M NH, solution vs. in pure water because the Ksp of AgCl is a constant at 25°C. D) 9. Calculate the molar solubity of AgBrts) in 0.500 M NH, at 25°C. Kup of AgBr is 1.8 x 10-5, K of Ag(NHs)2" is 1.7 x 10 A) 8.7 x 104 M B) 1.2x 10-3 M C) 4.2 x 10-7 M...