Lab #2: Gas Chromatography Theory behind gas chromatography What do all types of chromatography share in...
As you increase the gas chromatography column temperature, analytes’ ______________ increases and stationary phase solubility _______________. A) boiling point; increases B) vapor pressure; decreases C) vapor pressure; increases D) retention time; increases E) retention time; decreases
1. A mixture of four alkenes (1-decene, 1-heptene, 1-nonene, and 1-octene) was analyzed by gas chromatography. Below, on the line, list the four alkenes in order of increasing retention time: 2. At 760.0 mm atmospheric pressure, a binary liquid mixture of components A and B gives the temperature composition diagram shown below. The liquid curve plots boiling point vs. composition of the liquid mixture. The vapor curve plots temperature vs. equilibrium vapor composition. A horizontal line on the diagram, such...
Calculate the vapor pressure of 3-pentanone (b.p. 102.0 °C) at the gas chromatography column temperature of 96.0"C using the form of the Clausius-Clapeyron equation shown below, P1 P. vap where R is the ideal gas constant, ???? is the enthalpy of vaporization, T1 and T2 are two different temperatures, and P1 and P2 are the vapor pressures at the respective temperatures. The enthalpy of vaporization can be estimated using Trouton's rule, ??'vap-(88 J mol-1 K-1), Tp. Number Torr Calculate the...
PART 1: In a gas chromatography experiment using a non-polar stationary phase A) solutes are eluted in order of increasing boiling point. B) solutes are eluted in order of increasing vapor pressure. C) solutes are eluted in order of increasing polarity. PART 2: You can improve the separation of components in gas chromatography by A) raising the temperature of the injection port. B)raising the temperature of the column isothermally. C) raising the temperature of the column programmatically.
In gas chromatography, when two compunds have very similar retention times, explain what change could be made to 1. pressure 2 heating ramp rate and 3 length of column to achieve a better separation. thankyou!
In my organic chemistry lab we are performing a gas chromatography experiment and I need help with our prelab assignment, thanks! Question 3 1 pts If compound A elutes (comes off) a GC column earlier than compound B in a temperature gradient GC run. What can be inferred about their respective boiling points? Compound A probably has a lower boiling point than that of compound B. Compound A and B have the same boiling point. Elution time does not correlate...
Chromatography Basics Multiple Choice: Answer the following multiple choice questions about Chromatography Basics (SHOW WORKING): 1) In a given chromatographic column, A) different solutes behave as if there are a different number of theoretical plates for each. B) the number of theoretical plates is the same for all solutes. C) efficiency is improved by increasing plate height. 2) What useful information can be found from a Van Deemter plot? A) The selectivity factor B) Optimum mobile phase flow rate C) Optimum...
LAB 2A SEPARATION OF LIQUIDS BY SIMPLE DISTILLATION ANALYSIS BY GAS CHROMATOGRAPHY LAB 2A Pre-Lab Questions NAME DATE LAB SECTION Answer the following questions in the pre-lab section of your notebook. 1. Which compound, acetone or 1-propanol, has the higher boiling point? Why? 2. Do you expect acetone to be soluble in 1-propanol? Why or why not? Model: For this question, you will be graded on completion, rather than correctness of the model. In the post-lab, you will be asked...
9 VII. Gas Chromatography 1. The organic mixture to be separated on the GC is injected into the GC as a (gas, liquid, or solid). 2. The typical volume of mixture injected into a GC is 1-10 (microliters, milliliters, or deciliters). 3. Immediately upon entering the injection port the mixture is_ _(solidified, condensed, or vaporized). (heated, cooled, maintained at room 4. The event described in #3 occurs because the injection port is temperature). 5. An inert gas, referred to as...
"Vapor Pressure of Water" assignment: VAPOR PRESSURE OF WATER INTRODUCTION All liquids exist in equilibrium with the vapor state. As temperature increases, this equilibrium shifts more and more in favor of the vapor until one reaches the boiling point, at which all liquid is converted to gas. The pressure exerted by the vapor over the liquid is known as its vapor pressure and is a function of temperature. Boiling occurs at the temperature at which the vapor pressure is equal...