First we must calculate the moles of salt and acid present, and then its concentration in the final solution:
nHCO2H = 3.58 g * (1 mol / 46.03 g) = 0.0778 mol
nKCO2H = 5.95 g * (1mol / 84.11 g) = 0.0707 mol
[HCO2H] = 0.0778 mol / 0.25 l = 0.3112 M
[KCO2H] = 0.0707 mol / 0.25 l = 0.2828 M
Finally we calculate the pH with the help of the Henderson-Hasselbach equation:
pH = pKa + Log ([KCO2H] / [HCO2H]) = 3.8 + Log (0.2828 / 0.3112) = 3.76.
pH = 3.76.
JA buffer is prepared by dissolving 3.58 g of for c acid (????) and 5.95 g...
#3 & #4 explanation please
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