For Ionic bonding, simple models for the attractive and repulsive potential energies exists: EA = -A/r ...
For Ionic bonding, simple models for the attractive and repulsive potential energies exists:
EA = -A/r and ER = B / (r8)
Calculat the equilibrium bond length in angstroms at zero Kelvin, assuming the following constants: A = 1.4 eV/nm and
B = 7.00e-6 eV/(nm8)
Homework Answers
At equilibrium, EA = -ER
=> 1.4 / r = 7.00 x 10-6 / r8
=> r7 = 5.00 x 10-6
=> r = 0.175 nm
=> r = 1.75 A ( since, 1nm = 10 A)
Add Answer to:
For Ionic bonding, simple models for the attractive and
repulsive potential energies exists:
EA = -A/r ...
For a K+–Cl– ion pair, attractive and repulsive energies EA and ER, respectively, depend on the...
For a K+–Cl– ion pair, attractive and repulsive energies EA and
ER, respectively, depend on the distance between the ions r,
according to EA = − 1.436 r ER = 5.8 × 10−6 r 9 For these
expressions, energies are expressed in electron volts (eV) per
K+–Cl– pair, and r is the distance in nanometers (nm). The net
energy EN is just the sum of the two expressions above (EN = EA +
ER). (a) Superimpose on a single plot...
1. For a pair of ions M*-X, the attractive and repulsive energies EA and Er (in...
1. For a pair of ions M*-X, the attractive and repulsive energies EA and Er (in eV/pair), respectively, depend on the distance between the ions r (in nm), according to the following equations: 1.5 EA r ER 6 x 10-6 r9 a. Write down the expression for the total energy En. (2 marks) b. Take the derivative of Ex (4 marks) C. Calculate the equilibrium distance ro given that it is be distance at which en is minimum. (6 mark)...
For an Na+Cl- ion pair, attractive and repulsive energies EA and ER, respectively, depend on the...
For an Na+Cl- ion pair, attractive and repulsive energies EA and ER, respectively, depend on the distance between the ions (r), according to EA = - 1.436/r ER = 7.32 * (10^-6 / r^8) For these expressions, energies are expressed in electron volts (eV) / Na+Cl- ion pair, and r is the distance in nanometers (nm). The net energy, EN, is the sum of the EA and ER. a) Using graphical software (e.g. Matlab or Excel), create a single plot...
10. For a Na +Cl-ion pair, attractive and repulsive energies Ea and ER, respectively depend on...
10. For a Na +Cl-ion pair, attractive and repulsive energies Ea and ER, respectively depend on the distance between the ions r, according to 7.32 × 10-6 EA 1.436 For these expressions, energies are expressed in electron volts per Na+ Cl- pair, and ance in nanometers. The net energy Ev is just the sum of the preceding two expressions. (a) Superimpose on a single plot EN,FR, and EA versus r up to 1.0 nm. (b) On the basis of this...
2.16 Consider a hypothetical X-Y ion pair for which the equilibrium interionic spacing and bonding energy...
2.16 Consider a hypothetical X-Y ion pair for which the equilibrium interionic spacing and bonding energy values are 0.38 nm and -6.13 eV, 2.14 The net potential energy between two adjacent ions, EN, may be represented by the sum of Equations 2.9 and 2.11; that is, B EN= (2.17) r Calculate the bonding energy Eo in terms of the parameters A, B, and n using the following procedure: 1. Differentiate EN with respect to r, and then set the resulting...
Answer to Problem 2.19 Bonding Forces and Energies 2.13 Calculate the force of attraction between a...
Answer to Problem 2.19
Bonding Forces and Energies 2.13 Calculate the force of attraction between a Ca2+ and an O on the centers of which are separated by a distance of 1.25 nm. 2.14 The net potential energy between two adja- cent ions, EN, may be represented by the sum of Equations 2.8 and 2.9; that is, A B Calculate the bonding energy Eo in terms of the parameters A, B, and n using the follow ing procedure: 1. Differentiate...
For a K+–Cl– ion pair, attractive and repulsive energies EA and
ER, respectively, depend on the distance between the ions r,
according to EA = − 1.436 r ER = 5.8 × 10−6 r 9 For these
expressions, energies are expressed in electron volts (eV) per
K+–Cl– pair, and r is the distance in nanometers (nm). The net
energy EN is just the sum of the two expressions above (EN = EA +
ER). (a) Superimpose on a single plot...
1. For a pair of ions M*-X, the attractive and repulsive energies EA and Er (in eV/pair), respectively, depend on the distance between the ions r (in nm), according to the following equations: 1.5 EA r ER 6 x 10-6 r9 a. Write down the expression for the total energy En. (2 marks) b. Take the derivative of Ex (4 marks) C. Calculate the equilibrium distance ro given that it is be distance at which en is minimum. (6 mark)...
10. For a Na +Cl-ion pair, attractive and repulsive energies Ea and ER, respectively depend on the distance between the ions r, according to 7.32 × 10-6 EA 1.436 For these expressions, energies are expressed in electron volts per Na+ Cl- pair, and ance in nanometers. The net energy Ev is just the sum of the preceding two expressions. (a) Superimpose on a single plot EN,FR, and EA versus r up to 1.0 nm. (b) On the basis of this...
2.16 Consider a hypothetical X-Y ion pair for which the equilibrium interionic spacing and bonding energy values are 0.38 nm and -6.13 eV, 2.14 The net potential energy between two adjacent ions, EN, may be represented by the sum of Equations 2.9 and 2.11; that is, B EN= (2.17) r Calculate the bonding energy Eo in terms of the parameters A, B, and n using the following procedure: 1. Differentiate EN with respect to r, and then set the resulting...
Answer to Problem 2.19
Bonding Forces and Energies 2.13 Calculate the force of attraction between a Ca2+ and an O on the centers of which are separated by a distance of 1.25 nm. 2.14 The net potential energy between two adja- cent ions, EN, may be represented by the sum of Equations 2.8 and 2.9; that is, A B Calculate the bonding energy Eo in terms of the parameters A, B, and n using the follow ing procedure: 1. Differentiate...
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