Question

Consider the two following half reactions: Fe(OH)3(s) + 3H3O+ + e- <-> Fe2+(aq)+ 6H2O EoH= 1.06...

Consider the two following half reactions:

Fe(OH)3(s) + 3H3O+ + e- <-> Fe2+(aq)+ 6H2O EoH= 1.06 V; peo= 17.9

NO3-(aq) + 10H3O+ + 8e- <-> NH4+(aq)+ 13H2O EoH= 0.88V; peo= 14.9

(a)Which reaction would you expect to be the oxidation and which the reduction under standard conditions?

(b)Write the full balanced reaction.Show your work.

(c)Assuming that the concentrations ofFe2+(aq), NH4+(aq), and NO3-(aq) are all 10-5M and pH 7, calculate the pE for the redox reaction in (b).

(d)Comment on what the calculated pE in (c) tells you about the environment in which this reaction is occurring.

0 0
Add a comment Improve this question Transcribed image text
Answer #1

a)

NO3- reaction will go for oxidation and Fe(OH)3 will go for reduction under standard conditions based on provided values of reduction potentials.

b)

8Fe(OH)_{3}(s)+24H_{3}O^{+}+8e^{-} ightleftharpoons 8Fe^{2+}(aq)+48H_{2}O

NHỊ (aq) + 13H2O-Ņ03 (aq) + 10H3O+ + 8e

Adding above two equations,

8Fe(OH)_{3}(s)+NH_{4}^{+}(aq)+14H_{3}O^{+} ightleftharpoons 8Fe^{2+}(aq)+NO_{3}^{-}(aq)+35H_{2}O

Eo Om 8 × 1.06-0.88-7.6 V

2+18N r-0.05 FNO logo( INHillH30114

E = 7.6-0.0:09log10(10T) 10-45 10-103

8.028 y

Add a comment
Know the answer?
Add Answer to:
Consider the two following half reactions: Fe(OH)3(s) + 3H3O+ + e- <-> Fe2+(aq)+ 6H2O EoH= 1.06...
Your Answer:

Post as a guest

Your Name:

What's your source?

Earn Coins

Coins can be redeemed for fabulous gifts.

Not the answer you're looking for? Ask your own homework help question. Our experts will answer your question WITHIN MINUTES for Free.
Similar Homework Help Questions
ADVERTISEMENT
Free Homework Help App
Download From Google Play
Scan Your Homework
to Get Instant Free Answers
Need Online Homework Help?
Ask a Question
Get Answers For Free
Most questions answered within 3 hours.
ADVERTISEMENT
ADVERTISEMENT
ADVERTISEMENT