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Acids and bases

Below is a \(\log C-p H\) diagram for \(10^{-3} M\) hydrogen sulfide \(\left(\mathrm{H}_{2} \mathrm{~S}\right),\) a diprotic acid, with \(\mathrm{p} K_{a 1}=6.99\) and \(\mathrm{pK}_{a 2}=12.92 .\)

a. Label the lines with the species they represent, and assign correct values to the axes.

b. Draw lines for \(\mathrm{H}^{+}\) and \(\mathrm{OH}^{-}\) on the diagram.

c. What is the \(\mathrm{pH}\) of a solution made by mixing \(10^{-4} \mathrm{M}  \mathrm{NaHS}\) and \(9 \times 10^{-4} \mathrm{M}\) \(\mathrm{H}_{2} \mathrm{~S} ?\)

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