Question

Consider a voltaic (galvanic) cell with the following metal electrodes. Identify which metal is the cathode and which is the anode, and calculate the cell potential. (Use the table of Standard Electrode Potentials.) (a) Sn(II) and Co(II) O Sn (II) Co(II) Anode Sn(II) O Co(II) cell =

I need help finding the E cell! I keep getting it wrong!

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Answer #1

a)

from data table:

Eo(Co2+/Co(s)) = -0.28 V

Eo(Sn2+/Sn(s)) = -0.14 V

the electrode with the greater Eo value will be reduced and it will be cathode

here:

cathode Sn(II)

anode is Co(II)

Eocell = Eocathode - Eoanode

= (-0.14) - (-0.28)

= 0.14 V

Answer: 0.14 V

c)

from data table:

Eo(Cd2+/Cd(s)) = -0.40 V

Eo(Au3+/Au(s)) = 1.50 V

the electrode with the greater Eo value will be reduced and it will be cathode

here:

cathode is Au(III)

anode is Cd(II)

Eocell = Eocathode - Eoanode

= (1.50) - (-0.40)

= 1.90 V

Answer: 1.90 V

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