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Consider a system consisting of 3.0 mol CO2(g), initially at 35°C and 9.0 atm and confined...

Consider a system consisting of 3.0 mol CO2(g), initially at 35°C and 9.0 atm and confined to

a cylinder of cross-section 100.0 cm2. The sample is allowed to expand irreversibly and adiabatically against an external pressure of 2.5 atm until the piston has moved outwards through 25 cm. Assume that carbon dioxide may be considered a perfect gas with CV,m = 28.8

J K–1 mol–1, and calculate (a) q, (b) w, (c) ΔU, (d) ΔT, (e) ΔS.

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