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A reversed phase HPLC column is eluted with 1:1 MeOH/H2O and tm is determined to be...

A reversed phase HPLC column is eluted with 1:1 MeOH/H2O and tm is determined to be 0.22 min. After injection of an unknown, peaks are observed at 0.22 min, 3.6min, 6.6 min, and 25.4 min.

a) Which of the analyte peaks corresponds to the least polar compound?

b) Calculate a new solvent mixture to cause this compound to elute at 15 min.

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