give the product of the following reactions 5. Give the product of the following reactions (60...
1. Give the major product of the following reactions, write NR. if no reaction happens. Indicate the stereochemistry if necessary CHCI KOC(CH3). (CH),COH 1. conc. HBr, heat 2. KOBU, HOBU 1. NaOM, MOH CI 2. BICN 1. 1 eq. BH3. THE 2. H2O2, NaOH, H2O 3. Hg(OAC), MeOH 4. NaBH4, NaOH, H2O 1. conc. HCI 2. LDA, THF 3. O. CH,OH 4.(CH), 1. Hg(OAC), THE 2. NaBH, NaOH, H2O > OH (Hint: product has a bicyclic ring)
1. PREDICT THE PRODUCT: Provide the structure of the major product expected from the following reactions or reaction sequences. Make sure you account for any regio- and/or stereochemistry! (24 pts.) H2O 1. Hg(OAC), CH, OH 2. NaBH H2SO4 H20 1) BH-THF 2) H202, KOH HBr Bry, H2O HBr ROOR 1. BH3-THF 2. H2O2, NaOH H20, H2SO4 1. NaNH2 H2 H-CEC-CH2 CH2 CH3 2. CH CH Br Lindlar cat 1. Sia BH-THF 2. H2O2, H2O
draw the major product of the following reactions.
nos 1) R-BH 2) H.O., NaOH 3) NBS, heat (I eq) 1) KMnO4, heat 2) Na, NH3, CH OH 3) Br, light (I eq) 1) NBS, light 2) NEL 3) Br 4) NaNH (45) 5) HO
Predict the products, if any, of the following reactions. COOH (1) LiAlH (2) H2O* (b) CH B (1) NaCN (2) 40*, heat (1) SOCI2 (a) oct-4-ino KMnO4 H20 (warm , conc.) (2) AICI COOH Ph 10 O Na,Cr,O, H,SO4 BH CH,OHN_C6:0, 14,50. CHCH.–CH-COOH BH, CH,OH (1) CH,CH, -CH-COOH CH,OH KMnO4, H2O (warm, conc.) KMnO,H,O (hot , conc.)
2. Draw the major product for the following reactions.
6.Draw the final product for the following reactions
2. Draw the major product for the following reactions. 1) TCI 2) NaOEL, Heat 3) 0 4) DMS 1) NBS, heat (1 eq.) 2) NaNH, DMS0 3) KMnO4 (aq) NaOH, cold 4) NaCl acetic acid 1) , 2) H.O 3)Ni, 1, 150, 100 atm 1) R RH 2) H.O., NaOH 3) NBS, heat (I eq) 1) KMnO heat 2) Na, NH, CH,OH 3)...
For each of the following reactions, provide the product with proper stereochemistry if applicable. In addition, draw the arrow-pushing mechanism for the reaction. 1. CH HCI 2. CH HBr ROOR 3. CH, Н,0 H, SO 4. CH3 1. Hg(OA), 2. NaBH + 5. CH, 1. BH, THF 2. HO, NaOH
1. Give the major product of the following reactions, write N.R.
if no reaction happens. Indicate the stereochemistry if
necessary:
1. Give the major product of the following reactions, write N.R. if no reaction happens. Indicate the stereochemistry if necessary: CHCl3 KOC(CH3)3, (CH3)3COH 1. conc. HBr, heat 2. KOBU, HOBU ✓ 1. NaoMe, MeOH 2. BrCN 1. 1 eq. BH3, THE 2. H2O2, NaOH, H20 3. Hg(OAc)2, MeOH 4. NaBH4, NaOH, H20
Provide the major product(s) for the following reactions: Show Stereochemistry when necessary (10 points total) Br HBr CH2CI Br2 HBr Но ROOR CH,OH Н,о н* Н,о° 1) Hg(O,CCF3)2 CH,OH 1) BН, THF 2) H,О, NaOH, Нао 2) NaBH, NaOH 1) Hg(OAc) Н0, THF/ Hа Pd/C 2) NaBH, NaOH
4. Give the major organic product(s) for each of the following reactions or sequences of reactions. H Br 1. N.CN 2. NaOH,H,O, heat 3.H30 Ind o do CH,COOH 1. LiAlH, THF, heat 2.H,0 HO CH Br 1. NaCN, acetone 2.H30, heat h ome couco C:03, H30* он
3. Complete the following reactions of the compound shown by drawing the correct products with CORRECT stereochemistry if important (10 pts). + Br2 Brain H20 1. 03 2. Mezs Hipo H/Pd 1. Hg(OAC) in THF/water 2. NaBH4, NaOH 1. BH3-THF 2. H2O2, NaOH peroxyacid HBO HBr/peroxide 1. Os04 2. NaHSO3