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Draw detailed stepwise mechanisms to explain the two results shown below, and rationalize the difference. Ln- (PPh3)4 You may assume that your Pd(0) species that reacts with the substrate contains two phosphines and that two have dissociated . . Label your ligand type, EN, OS, and dn for each intermediate. .Make the system catalytic (ie, end up with a Pd(0) species) Me Br LnPd CO2Me Me CO2Me

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PPha Op PlBr Me oridatile additon T-comple fb me Me Poll untermediate Me pph9 RaselB) Pph3 Reduchiu e eliminaton

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