Consider the graph below, which is a plot of the relative energies of the various conformations...
The graph below is a plot of the relative energies of the various conformations of 0 60 120 180 240 300 360 Angle of rotation OA.Chloroethane O B. Ethane OC Propane OD. Butane (C1-C2 rotation) OE 1-Chloropropane (C1-C2 rotation) Refative Dhergy Which staggered Newman projection(s), looking down the C-2-C-3 bond (C-2 in front and C-3 in back), illustrates the following boxed compound? CH CH CH CH CH CH H CI H сн.CH II CHy CH CH CH HiC. H CH...
please answer ALL parts of the question Motion: Conformations by Rotations aswer the following questions about energy barrier to convert a gauche conformation into its "NTEGRATE THE SKILL -.4 a) Use the energy diagram in Figure 3.3 to answer the following 9 1,2-dichloroethane. i) What is the height of the energy barrier to convert anti-conformation? ii) What is the height of the energy barrier to convert an anti-c f the energy barrier to convert an anti-conformation into its gauche conformation?...
Question 6 (2 points) Consider the rotation around the C2-C3 bond of 2-methylbutane. Using the values listed below, calculate the energy corresponding to (eclipsed or staggered) conformations at each 60° rotation. Define the dihedral angle (6) as the angle between the H on C2 and the methyl group on C3. Begin at the O° dihedral angle (placing C2 in front and C3 in back) and turn clockwise the front carbon. H,H eclipsing interaction = 1 kcal/mol H,CH3 eclipsing interaction =...
'H 22. Given the following table of eclipse and gauche energy values (these are added strains to the molecule). Fill in all 6 newman projects for 2,2,3-trimethylpentane viewed down the C3-C4 bond. Then calculate the total energy of each newman projection and plot them on the graph below. H-H H-Me H-Bu Me-tBu Interaction Gauche Energy (kcal/mol) Eclipse Energy (kcal/mol) Me-Me 0.8 0 2.7 0.5 1.0 8.5 1.3 2.5 3.0 Conformational Energies 360 300 240 180 120 60
I already know how to do 1 and 2. if you could show me how to do number 3 on the graph above, and how to calculate the expected energy of the conformer please 1 60 120 180 240 300 360 Torsion angle (degrees) AE (kcal/mol) In the box below each molecule, draw Newman projections for the structures A, B, and C shown from the perspective indicated. For each Newman projection that you've drawn, indicate if there are any eclipsed...
ох 1. Provide the name of the following compounds. så stk 2. Provide the name of the following compounds. 3. Provide the line structure given the following names. A. 2,6,6,8-tetramethyl-5-neopentyldecane R. 7-methylbicycln[4.2.2]decane ох 4. A. Draw the Newman Projection of pentane looking down the C2-C3 bond in a stageered confirmation B. Draw an energy diagram showing the conformational analysis using the Newman Projection above (showing a 360 degree total rotation, 60 degrees at a time). Hint - see Figure 46,...
Which Newman projection corresponds to point A on the graph of potential energy vs rotation about the C2 Cz bond? Potential Energy s A 0 60 300 360 120 180 240 Degrees of Rotation CH; HI H H H CH; CIL HCH: нен H HH H CH CH H CH CIL 11 11 11 What is the major product of the following reaction? Br NaOMe, MeOH D Δ Ome A B C D 'D D H D B с D...
Q7.14: Triatomic species can take which two structures? Select all that apply? A tetrahedral B bent linear D octahedral А Q7.15: Which of the following is predicted to be used by the sulfur atom in SO3 based on valence bond theory? А sap B sp2 Csp3 D sp Q 7.15: Both VSEPR theory and valence bond predict the same geometry for XeO3. А True B False Q 7.15: According to valence bond theory, the structure C2H2 the two carbon atoms...