Question

thermochemistry

                     Ba (OH)2 (s) + 2 NH4Cl (s)  →  BaCl2 (s) + 2 NH3 (g)  +  2 H2O (l) 

DHf° (kJ/mol)   -626.56         -314.55            -495.73       -45.90       -285.83   

Mass of water

5.678 g

Ti

2.33

Tf

-21.33

a. calculate the heat lost when the mass of water (g) cools from Tto 0 °C.  This is q1.  This is the change in part A of the graph.

 

b. calculate the heat lost when the mass of water changes from liquid to solid (ice).  This is q2.  This is the change in part B of the graph.

 

c. calculate the heat lost when the water cools from 0 °C to Tf.  This is q3.  This is the change in part C of the graph.

 

d. calculate the total heat lost from the surroundings:  q1 + q2 + q3.

 

e. calculate the heat absorbed by the system.

 

f. calculate the value of DHrxn° for the reaction in the system.

 

g. calculate the number of moles of barium hydroxide in a reaction that absorbs the amount of heat you calculated in 5.

 

h. calculate the number of moles of ammonium chloride required to react with the mass of barium hydroxide calculated in 7. 

 

I. calculate the grams of each reactant required.


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