A certain atom has a doubly degenerate ground level pair and an upper level of four degenerate states at 450 cm^-1 above the ground level. In an atomic beam study of the atoms it was observed that 30 per cent of the atoms were in the upper level, and the translational temperature of the beam was 300 K. Are the electronic states of the atoms in thermal equilibrium with the translational states?
A certain atom has a doubly degenerate ground level pair and an upper level of four...
Problem 3. A certain atom has a doubly degenerate ground level pair and an upper level of four degenerate states at 450 cm-above the ground level. In an atomic beam study of the atoms it was observed that 30 per cent of the atoms were in the upper level, and the translational temperature of the beam was 300 K. Are the electronic states of the atoms in thermal equilibrium with the translational states?
Problem 2. A certain atom has a threefold degenerate ground level, a non-degenerate electronically excited level at 3500 cm, and a threefold degenerate level at 4700 cm-?. Calculate the partition function of these electronic states at 1900 K.
The NO molecule has a doubly degenerate excited electronic level 121.1cm-1 above the double degenerate electronic ground term. (a) Calculate the electronic partition function of NO at T=0K, T=298K and T=1000K. (b) Evaluate the populations of ground and excited states and (c) the mean electronic energy at 298K.
8. (10 pts) (a) (6 pts) Suppose a system consists of N noninteracting, indistin guishable, identical particles and that each particle has available to it only two quantum electronic states, whose energies are 0 and a. Find expressions for z, Z and U. Note: Because we don 't consider translational energy here, so the 1/N! should be om itted when writing Z in terms of z (b) (4 pts) For NO, the ground electronic level and the first exited electronic...
Lab Section: Experiment #11: The Atomic Spectrum of Hydrogen Advanced Study Assignment 1. Found in the gas phase, the beryllium trication, Be has an energy level formula analogous to that of the hydrogen atom, since both species have only one electron. The energy levels of the Belon are given by the equation E, = -2100-kl/mole n = 1.2.3. - Calculate the energies in kl/mole for the four lowest energy levels of the Belon. a kl/mole kl/mole kJ/mole kl/mole b. One...
EENG 245 Physical electronics HW 1 1) The NaCl crystal is cubic, and can be described as follows. Na atoms sit at the corners and faces of a cube, and Cl atoms sit in between two Na atoms. This means that a Clatom is found half-way along each of the cube edges, and there is a Cl in the center of the cube. (We could also have described the lattice by interchanging Na and Cl in the description above.) Another...
Solve the 4.5 problm.. The results of section 4.4 are
given above
4.5 Generalise the res sults of Section 4.4 to the case in which the level E is g , times degenerate and the level E, is g, times degenerate, and show that the Einstein coefficients satisfy the relations o ba 4.71] 3c in energ the e 4.4 THE EINSTEIN COEFFICIENTS We shall verify that [4.71] is the correct expression for the rate of spontaneous emission by using the...
Al is metal, silvery in colour, with a resistivity of 2.65 μΩ.cm at room temperature. it has the so-called face centred cubic (FCC) structure, in which the fractional coordinates of the atoms within the (conventional cubic, side length of a 4.046 A) unit cell are: (0,0,0), (12%,0), (12,0,%), (0,%,%) The intermetallic compound AbAu is bright purple in colour, has a melting point of 1060°C, is rather brittle, and has a resistivity of p-8 u2.cm.1 the repeating unit is also cubic...