Please see the image.
1. DRAW the monohalogenation products of the following reaction, including relevant sterochemistry of the products. T...
Denounce which products are made in the following reactions.
Include sterochemistry if relevant. If no reaction occurs write
I.R.
OH NaOH, H20 NH2 Naci o Naci
4. Draw the structures and provide the IUPAC names of the two allylic monohalogenation products of this reaction (3 pts.). NBS heat 5. Devise a synthesis of the molecule shown in the box from cyclohexane (3 pts.). 6. Rank the hydrogens by increasing ease of abstraction in a free radical halogenation reaction (2 pts).
provide the products for each reaction including any relevant
stereochemistry. if a pair of stereoisomers is produced, draw one
and write + enantiomer ir + diastereomer, whichever is
relevant.
1. CH, MgBr 2. H₂0" (Ph),Culi (R)-CBS + light 1. DIBAH 2. H, ... 1. Mgether 2. CO 3. H,0
Predict the products of the reaction. Draw all the
products of the reaction, including water if it is formed. If a
racemic mixture is expected, the product can be drawn without any
stereochemistry shown.
Conceptual Checkpoint 13.10 Predict the products for each of the following reactions. Draw ALL the products of the reaction, indc can be drawn without any stereochemistry shown. 13.10a Your answer is incorrect. Try again. Excess HBr Heat CH OH н.с edit CH Br H3C
5. Mechanism: (20 pts) Show the detailed reaction mechanism including all relevant arrows, intermediates, inorganic products, relevant resonance structures, and stereochemistry for the following reaction heat OH H-Br Step 1 step 2 Step 3 Step 4 Product(s) a. This is a Sx2/S1/E/Ez/ reduction / oxidation mechanism. b. What is the product if the starting alcohol is reacted with PBry? Product(s) with PBry c. Reaction with PBr; is a S2/S1/E/Ez/reduction / oxidation mechanism.
5. Mechanism: (20 pts) Show the detailed reaction mechanism including all relevant arrows, intermediates, inorganic products, relevant resonance structures, and stereochemistry for the following reaction. heat OH H-Br step 1 step 2 step 3 step 4 Product(s) a. This is a S2/Sx1/E/E2/ reduction / oxidation mechanism. b. What is the product if the starting alcohol is reacted with PBrz? Product(s) with PBrz c. Reaction with PBr3 is a S2/S1/Ej / E2 / reduction / oxidation mechanism.
Predict how many stereoisomeric aldol products will be produced
in the following aldol addition. Draw the structures of all
the aldol products. Show all relevant sterochemistry.
NaoEVELOH aldol products 20 °C
IV. Products: Fill in the major product(s) including stereochemistry if relevant. (1 pom stereochemistry if relevant. (15 points) Br2 + H BY — light Iz o o other -2 na Matt cie - on selline on no
Draw the major product(s) or reagents for the following reactions.
Pay attention to sterochemistry where appropriate.
1. Draw the major product(s) or reagents for the following reactions. Pay attention to stereochemistry where appropriate. Put a box or circle around your final answer. xs ethyl lodide ..^ NH Note 3 oy bolo NO2 1. Sn, HCI 2. NaHCO, 3. [H"). NaBH,CN. acetone 1. КОН NH BI 3. HANNHKOH heat 1. HNO, HASO 2. Sn, HCI 3. NaOH 4. NaNO,, HCI 5....
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4. (10 pts) Draw all possible products for the following reaction including stereoisomers. Note that the addition occurs through a "syn" mechanism. Is the product solution optically active (yes or no)? 1. BAHATHF 2. NaOH, HO (8 pts) Provide a complete mechanism for the reaction below and include lone-pairs of electrons and formal charges. Show all products formed including stereoisomers. Is the product solution optically active (yes or no)? Bras 11. (8 pts) Draw all four regiochemical...