85 Deduce the stereochemical course of each of the following reactions. Where more than one organic...
12. REACTIONS: Give the MAJOR organic products of each of the following reactions. India stereochemistry where appropriate. [3 points each] 1) NaH 2) CH-CH2 CH,CH,OH HASO. PBrg 1) BH, THE 2) H202 / OH 1) TCI. pyridine 1) NBS 2) DMSO,H2O
For each of the following reactions, draw the structure of the major organic product in the box provided. Each numbered set of reagents above or below the arrow represents a complete separate reaction. For multi-step reactions, give only the structure of the final product. КОН (alc) Br b) KOtBu HOtBu Br THE H2SO4 OTS КОН (ale) CH,CH Show Specific Stereochemistry CH(CH3)2 HCI H- CH CH_CH KOH (ale) Show Specific Stereochemistry NaOCH HOCH KO:Bu HOBu
Indicat II. REACTIONS: Give the MAJOR organic products of each of the following reactions. Stereochemistry where appropriate. [3 points cach] нусЗн H. CH CH,CH,OH H2SO NBS DMSO, HO " Học &H 1) NaOCH 2) H₃0 нс" н OH 1) TSCI, pyridine HD 2 0
Draw the organic product for each of the following reactions. If more than one product is expected, be sure to indicate the major product. Show stereochemistry where appropriate. AICl NO2 heat 1) NaNH, N,(liq) 2) H20 Cl SOH I) HONO2,HSO SO3H 2) H0 heat 3) HyO*, Fe 1) Br2, heat light 2) KOH (alc) heat 3) NBS, heat light 4) KOH (ale) heat CN heat
plete the following reactions, providing the proper stereochemistry where required. If more than one product is possible, indicate the major product. a) ros. Br CH3 -CH; 1) BH THE 2) H20. NaOH -CH₂ ROOR RCO,H t.tt 1T 1) Hg(OA), H2O 2) NaBH 1. Provide the IUPAC name for the following molecule: 2. Draw the structure of Z-4-Bromo-5-methyl-4-hepten-2-yne: 3. Write down the major product(s), or the other reactant(s), of the following rea stereochemistry (wedge-and-dash) where appropriate: Xs HBr
C. REACTIONS: (8 points each; 40 points total) For each of the following reactions or series of reactions, draw the final major organic product, reactant, or reagents in the box. Be sure to indicate STEREOCHEMISTRY where pertinent. In multiple step reactions, you may place intermediate products below the reaction for partial credit. 1. NH2 2. 1) NBS, hv 2) NaCN 0.5 eq 3) NaOH, H20 4) HCI 3. 1) NaBH4 2) MCPBA 3) NaOH 4) excess acetic acid, H+
11. Give the MAJOR organic products of each of the following reactions. Indicate stereochemistry of th products where appropriate. [3 points each-15 total] K* "O Н.О . Na OCH THF HO CH-CH2O Na DMF Total points this page
Orgo chem help please Fill in the major organic product or products for the following reactions. Make sure to indicate stereochemistry where appropriate. Label each reaction with the mechanism used to get to the product (SN1, SN2, etc) Br H2O Br Br Br Br Br OH Heat Br Draw the complete mechanism for the first reaction (as practice you should draw the mechanism for all of them, based on what we learned in class)
Complete each equation below by drawing the structure of the organic reactant(s) or product(s) that best fit(s) the reaction depicted. Be sure to show stereochemistry correctly, where appropriate. 1) NaOEt, EOH 1) NaOH, H2O 2) HCI, H,0 Br 3) heat 3) HCUH, 1) HCI но он 1) Mg HOI, HO HOY Dean-Stark Trap 1. NaOEt 1. SOCI 2. EtOH 3.0.5 eq. NaOEt 2 HyN 4.HO (3 and 4 are a Major Reaction from Ch. 19)
4. Complete the following reactions, providing the proper stereochemistry where required. If more than one product is possible, indicate the major product. a) Bry CH Но b) 1) ВН THF CH3 2) Н,О, NaOH Hа сн, Pd сн, d) Нer ROOR e) RCO H 1) Hg(OAch, H2O 2) NaBH З/19