Draw the organic product for each of the following reactions. If more than one product is...
For each of the following reactions, draw the structure of the major organic product in the box provided. Each numbered set of reagents above or below the arrow represents a complete separate reaction. For multi-step reactions, give only the structure of the final product. КОН (alc) Br b) KOtBu HOtBu Br THE H2SO4 OTS КОН (ale) CH,CH Show Specific Stereochemistry CH(CH3)2 HCI H- CH CH_CH KOH (ale) Show Specific Stereochemistry NaOCH HOCH KO:Bu HOBu
Part 2. Predict the Organic Products. Predict the major organic product(s) for each of the following reactions. Be sure to show stereochemistry when appropriate. (3 points each) 1) NaNH / NH3 2) CH31 1) BH3 / THE 2) H2O2/NaOH/H20 1) OsO4 / THE 2) Has | 1) NaNH / liq. NH3 2) H20
Draw the structure of the major principal organic product in each of the following reactions. Include correct relative stereochemistry. You don’t need to draw both enantiomers. NaOH BH3 THF H202, H20 HgSO4 H2SO4 H20 heat 1 mol Br2 LiBr HOAc
provide the major organic product for the following pis). a.) H H2Cro acetone b.) 1. XS KMnO4 / KOH/H2O1A 2. H30* c.) XS NaBH4, H20 ОН I 1. XS LIAIH/THF/-78 °C 2. H20 H ОН NaNH / liq NH3
Draw the major product for the following reactions. -OH 2. Draw the major product for the following reactions. 1) TSCI 2) NaOEt, Heat 3) O; 4) DMS 1) NBS, heat (I cq.) 2) NaNH, DMSO 3) KMnO4 (aq) NaOH, cold 4) NaOCI, acetic acid 1) O 2) H,0 3)NI, H, 150, 100 atm 1) RBH 2) H.O, NaOH 3) NBS, heat (I eq) 1) KMnO heat 2) Na, NH, CH OH 3) Bry, light (I eq) 1) NBS, light 2)...
II. Draw the structure for the major organic product of each of the following reactions. 11. Ç(CH3) 30 1) PhČCI, AICI: 2) Et2NH, H2, Raney-Ni, heat 12. ÇO2Me 1) EtMgBr (2 equiv.) 2) H20, H30+ 13. o CNH2 1) Br2, NaOH, H20 O 2) (CH3)2CHČCI, pyridine 14. Br2, H20 CHO HOEH H -OH H-OH HOEH CH2OH
2. Draw the major product for the following reactions. 6.Draw the final product for the following reactions 2. Draw the major product for the following reactions. 1) TCI 2) NaOEL, Heat 3) 0 4) DMS 1) NBS, heat (1 eq.) 2) NaNH, DMS0 3) KMnO4 (aq) NaOH, cold 4) NaCl acetic acid 1) , 2) H.O 3)Ni, 1, 150, 100 atm 1) R RH 2) H.O., NaOH 3) NBS, heat (I eq) 1) KMnO heat 2) Na, NH, CH,OH 3)...
2. Draw the major organic product of each of the reactions. HBr, CH3OOCH3, heat OsO4, TBHP, H20 1. BH3-THE 2. H2O2, KOH, H20 1.03 2. DMS
3. (5) Complete the following reactions by drawing the structure of the principal organic product formed Ph Cl trace NaOH EtOH heat Br,Zn, THF Ph H dil dil Hyo at H,SO beatTHF (workup) HgClh, H20 CaCO3, CHCN BuLi, THFH NaH, OCHs dil H O heat (1.0equv) (workup) 0 NaOEt trace NaOEt EtOH, heat EtOH
3. Complete each of the following reactions. Draw the structure of the organic product or products in the space provided. Show stereochemistry if appropriate. (3 points each) SN2 reaction (a) (CH3)CHCH2Cl + NaCN Sn1 reaction (b) (CH3)CHCH,CI + NaCN (C) M Sn2 reaction ¢l + NaOH - ACH. E1 reaction (d) (CH3)3CCH,OH + HCI major product Ez reaction Cl + NaOH - LCH3 н Ereaction Cl + H20