2. Why the secondary amines RR'NH do not give diazonium salts? (6pts) CI R'RN—H + NaNO,...
Explain why primary and secondary amines form hydrogen bonds but tertiary amines do not?
provide a mechanism for both of the reactions provided. why can secondary or tertiary amines not be formed using this reaction? 1. Complete a mechanism for both pathways below, the hydrolysis (use acidic or basic conditions - note which is used) and the Ing- Manske procedure. Provide intermediates with arrows for each step. H2O .COH + RNH2 Hoor HO "co₂H oa aq. H2NNH2 2. Why can this reaction only form 1 (primary) amines, not 2 (secondary) or 3 (tertiary)?
1) Classify the following amines me nrimary secondary, tertiary or quaternary. Give the names for as many of the compounds you can 2) Which of the following amines is the highest and lowest basicity. 3) Write the products for the following acid-base reactions. a) + CH3COOH Pyridine acetic acid Anilinium chloride pyrrolidine
CH3 CH2 Secondary amines add to aldehydes and ketones to give enamines. Enamines are formed in a reversible, acid-catalyzed proces nucleophilic addition of the secondary amine to the carbonyl group, followed by transfer of the proton to yield a neutral carbinolanine Prosonation of the hydroxyl group converts it into a good leaving group, is no Instead, a proton is lost from the neighboring carbon to form an enamine. p, however there is no hydrogen left on the nitrogen to be...
Question 1: draw a mechanism for each of the reactions. Explain why the different amines create different products. Question 2: Explain the product distribution. primary vs. secondary or tertiary amines and their corresponding products. 1. Draw a mechanism for each of the transformations (primary and secondary amines). Explain why the two different amines lead to different molecules. NaOH RNH2 + CHCI 1° amine R-NEC RNH + CHCI- 2º amine HNR2 2. What are some likely reasons that contribute to this...
Which question do you know? Questions about amines (for students no. 2, 6, 8, 9) 1. Give the products of the reaction: a. diethylamine + acetic anhydride b. triethylamine + methyl iodie C. Aniline + H2SO4 d. Aniline + bromine/H,0 2. How to distinguish between : a. n-butylamine and triethylamine b. aniline and diethylamine 3. How to obtain (in one or more steps): a. Aniline from benzoic acid b. N-methylaniline from nitrobenzene 4. Sort the following amines according to increasing...
Why do C-H bonds decrease in strength in R-H when R goes from primary to secondary to tertiary, as stability increases? I thought the more stable the bond is, is the stronger the bond.
Convert playlist Diction QUESTIONS 1. (2 Points) Why is it essential to keep the diazonium salt at zero degrees while you are preparing the sodium 2-naphthoxide solution? 2. (2 Points) Would you need to use sodium carbonate for the diazotization of meta- nitroaniline? Explain your answer. 3. (2 Points) What would be the IUPAC name for the azo dye if you would have used p-chloroaniline instead of sulfanilic acid? Experiment 12 4. (4 Points) Calculate the theoretical yield for Orange...
CH3 H 2. In the reaction below, what type of reaction occurred? A. E2 - H₃C B. E1 slow step C. 5 2 HC—C—CI- (-CI) D.S 1 CH3 E. None of above Nuc: CH) → H3C—C—OH HC CH
signment: Amines beint days 2/30 answered H23.8 - Level 3 Homework. Unanswered Which of the following reaction schemes would not give the product indicated? NaN, H2, Pt A CI N NH 1. H,O, heat 2. NaOH (work-up) 1. KOH B NH 2. ΝΗ, 0 CI С NaCN 1. LIAIH: 2. H2O CI CN NH D NH OH 1. SOCI 2. NHS 1. LIAIHE 2. H. o NH PE DELL