Homework Answers
If you observe the mechanism, two times protonation occurs on Nitrogen hence it always gives primary amine.
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provide a mechanism for both of the reactions provided. why can secondary or tertiary amines not be formed using this r...
H2O COH + RNH2 H+ or O HO- COH on on КОН N-H + R-X N-R Ο RNH2 aq. H2NNH2 ΝΗ Why can this reaction not be used to form 2...
H2O COH + RNH2 H+ or O HO- COH on on КОН N-H + R-X N-R Ο RNH2 aq. H2NNH2 ΝΗ Why can this reaction not be used to form 2 or 3 amines? Draw a reasonable mechanism for the hydrolysis (acidic or basic) and the Ing- Manske procedure.
H2O COH + RNH2 H+ or O HO- COH on on КОН N-H + R-X N-R Ο RNH2 aq. H2NNH2 ΝΗ Why can this reaction not be used to form 2...
H2O COH + RNH2 H+ or O HO- COH on on КОН N-H + R-X N-R Ο RNH2 aq. H2NNH2 ΝΗ Why can this reaction not be used to form 2 or 3 amines? Draw a reasonable mechanism for the hydrolysis (acidic or basic) and the Ing- Manske procedure.
Question 1: draw a mechanism for each of the reactions. Explain why the different amines create...
Question 1: draw a mechanism for each of the reactions.
Explain why the different amines create different products.
Question 2: Explain the product distribution. primary vs.
secondary or tertiary amines and their corresponding
products.
1. Draw a mechanism for each of the transformations (primary and secondary amines). Explain why the two different amines lead to different molecules. NaOH RNH2 + CHCI 1° amine R-NEC RNH + CHCI- 2º amine HNR2 2. What are some likely reasons that contribute to this...
Please provide a mechanism that includes the formation of both products. Why is isoborneol formed more in the reduction...
Please provide a mechanism that includes
the formation of both products.
Why is isoborneol formed more in the reduction reaction? How
would product distribution change if methyl groups were missing
from camphor?
NaBH4 MeOH -OH OH Borneol Camphor Isoborneol
20) Part 1: Provide a step-by-step mechanism (using arrows to show electron movement) to show how...
20) Part 1: Provide a step-by-step mechanism (using arrows to show electron movement) to show how the below reaction occurs. Be sure to draw ALL intermediates and movement of electrons to appropriately justify the given product. NOTE: It is not necessary for you to add other reagents that are not shown OR include other possible products that can be formed under the given reaction conditions. (4 points) CI OH + H2O Part B: Clearly draw and fully label an energy...
1. Provide the products of the reaction below and a detailed reaction mechanism using curved arrows...
1. Provide the products of the reaction below and a detailed reaction mechanism using curved arrows to indicate the movement of electrons. (a) (b) КОН (c) Note that formation of 4- or 7-membered rings is disfavored. Hiyo KOH acidie workup 2. An interesting problem that involves a bit of review (imines and Grignard chemistry) and application of what you previously learned to a new reaction: The Carbon of an imine functional group (i.e. R.C-NR) is sufficiently electron deficient to be...
MSISTRY 203-204 Grganic Chemistry Lab Manual 3 4 EXPERIMENT #9 The Preparation of t Butyl Chloride A tertiary carbonium ion is more rapidly formed than a secondary or primary carbonium ion. Onc...
MSISTRY 203-204 Grganic Chemistry Lab Manual 3 4 EXPERIMENT #9 The Preparation of t Butyl Chloride A tertiary carbonium ion is more rapidly formed than a secondary or primary carbonium ion. Once formed, a tertiary carbonium ion is stabilized by charge dispersal to a greater extent than a secondary or primary carbonium ion. It therefore has a longer life expectancy. Primary carbonium ions, protons, may exist in solution only in solvated form have any free existence, they dehydration reaction and...
1. In both the sodium iodide test and the silver nitrate test, why does 2-bromobutane react faster...
1. In both the sodium iodide
test and the silver nitrate test, why does 2-bromobutane react
faster than 2-chlorobutane?
Bromine is a better leaving group since it is a weaker base than
chlorine is.
2. a. Why does benzyl chloride react under both
SN1 and SN2 conditions?
Benzyl
chloride is a primary alkyl halide, hence reactive under SN2
conditions.
The
primary carbocation formed due to the departure of Cl- is
stabilized by the pi electrons in the benzene ring.
b. Why is...
Questions and Problems 553 ation for the reaction that would produse cach of the following amines...
Questions and Problems 553 ation for the reaction that would produse cach of the following amines b. N.Methylpropanamine c. N.N-Diethylpentanamine 15.37 Briefly explain why the lower molar massamines (lewer than five carbons) exhibit appreciable solubility in water 15.38 Why is the salt of an amine appreciably more soluble in water than the mine from which it was formed 15.39 Most drugs containing amine groups are not administered as the mine but rather the amount you suggeste son why? 15.40 Why...
Can you help me determine if I am correct and help me find the ither answers...
Can
you help me determine if I am correct and help me find the ither
answers to this functional group lab worksheet?
18 w paper 1 we by addin trecome char Discussion of Properties and Test Ora general undergo dition reactions, whereas by substitution reactions. These two types of d e beds and womate compounds we characterized described in equation form as follows: action Addition Reaction Substitution Reaction (Note: numbers in boxes to the left refer to w in the...
H2O COH + RNH2 H+ or O HO- COH on on КОН N-H + R-X N-R Ο RNH2 aq. H2NNH2 ΝΗ Why can this reaction not be used to form 2 or 3 amines? Draw a reasonable mechanism for the hydrolysis (acidic or basic) and the Ing- Manske procedure.
H2O COH + RNH2 H+ or O HO- COH on on КОН N-H + R-X N-R Ο RNH2 aq. H2NNH2 ΝΗ Why can this reaction not be used to form 2 or 3 amines? Draw a reasonable mechanism for the hydrolysis (acidic or basic) and the Ing- Manske procedure.
Question 1: draw a mechanism for each of the reactions.
Explain why the different amines create different products.
Question 2: Explain the product distribution. primary vs.
secondary or tertiary amines and their corresponding
products.
1. Draw a mechanism for each of the transformations (primary and secondary amines). Explain why the two different amines lead to different molecules. NaOH RNH2 + CHCI 1° amine R-NEC RNH + CHCI- 2º amine HNR2 2. What are some likely reasons that contribute to this...
Please provide a mechanism that includes
the formation of both products.
Why is isoborneol formed more in the reduction reaction? How
would product distribution change if methyl groups were missing
from camphor?
NaBH4 MeOH -OH OH Borneol Camphor Isoborneol
20) Part 1: Provide a step-by-step mechanism (using arrows to show electron movement) to show how the below reaction occurs. Be sure to draw ALL intermediates and movement of electrons to appropriately justify the given product. NOTE: It is not necessary for you to add other reagents that are not shown OR include other possible products that can be formed under the given reaction conditions. (4 points) CI OH + H2O Part B: Clearly draw and fully label an energy...
1. Provide the products of the reaction below and a detailed reaction mechanism using curved arrows to indicate the movement of electrons. (a) (b) КОН (c) Note that formation of 4- or 7-membered rings is disfavored. Hiyo KOH acidie workup 2. An interesting problem that involves a bit of review (imines and Grignard chemistry) and application of what you previously learned to a new reaction: The Carbon of an imine functional group (i.e. R.C-NR) is sufficiently electron deficient to be...
MSISTRY 203-204 Grganic Chemistry Lab Manual 3 4 EXPERIMENT #9 The Preparation of t Butyl Chloride A tertiary carbonium ion is more rapidly formed than a secondary or primary carbonium ion. Once formed, a tertiary carbonium ion is stabilized by charge dispersal to a greater extent than a secondary or primary carbonium ion. It therefore has a longer life expectancy. Primary carbonium ions, protons, may exist in solution only in solvated form have any free existence, they dehydration reaction and...
1. In both the sodium iodide
test and the silver nitrate test, why does 2-bromobutane react
faster than 2-chlorobutane?
Bromine is a better leaving group since it is a weaker base than
chlorine is.
2. a. Why does benzyl chloride react under both
SN1 and SN2 conditions?
Benzyl
chloride is a primary alkyl halide, hence reactive under SN2
conditions.
The
primary carbocation formed due to the departure of Cl- is
stabilized by the pi electrons in the benzene ring.
b. Why is...
Questions and Problems 553 ation for the reaction that would produse cach of the following amines b. N.Methylpropanamine c. N.N-Diethylpentanamine 15.37 Briefly explain why the lower molar massamines (lewer than five carbons) exhibit appreciable solubility in water 15.38 Why is the salt of an amine appreciably more soluble in water than the mine from which it was formed 15.39 Most drugs containing amine groups are not administered as the mine but rather the amount you suggeste son why? 15.40 Why...
Can
you help me determine if I am correct and help me find the ither
answers to this functional group lab worksheet?
18 w paper 1 we by addin trecome char Discussion of Properties and Test Ora general undergo dition reactions, whereas by substitution reactions. These two types of d e beds and womate compounds we characterized described in equation form as follows: action Addition Reaction Substitution Reaction (Note: numbers in boxes to the left refer to w in the...
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