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To measure the concentration of an aqueous solution of H.O an analytical Chemists endpoint with 72.9 ml 0.3200 Mpotassium per
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Answer

Type of reaction : redox

Element oxidised : O

Mass percent of H2O2 : 2.84%

Explanation

6H+(aq) + 5H2O2(aq) + 2MnO4-(aq) ------> 5O2(g) + 2Mn2+(aq) + 8H2O(l)

O is oxidized from -1 to 0

Mn is reduced from +7 to +2

Stoichiometrically, 2moles of MnO4- reacts with 5moles of H2O2

moles of MnO4- consumed = (0.2200mol/1000ml)×72.9ml = 0.016038mol

moles of H2O2 present in the sample = (5/2)× 0.016038mol = 0.040095mol

mass of H2O2 in the sample = 0.040095mol × 34.02g/mol = 1.364g

mass percent of H2O2 = (1.364g/48.0g)×100 = 2.84%

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