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One mole of sodium chloride is added to 100 ml of
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48- depression in freezing point is a colligative property which depends on only number of solute particles and not on nature of solute particles in a solution. Here NaCl break into Na+ and Cl- in solution, do effectively each one mole of NaCl gives 2 mol of particles in solution(vant hoff factor=2).

So twice more depression in case of NaCl becoz it gives 2 mol of particles whereas sugar gives only one mole in solution as it doesnot break

Hence option- B

49- B option is correct because in case of hypertonic solution more water is gven out.

50- 1 mol Na3PO4 gives 4 mol of particles, so 2 millimole would give 8 millimole of particles. Hence E is correct option.

51- B

52- N2:O2 = 4:1 when comparing their number of moles.

In terms of mass, this ratio is (4×28)/32

Hence mass% of O2 =(32×100)/(4×28 + 32) ~22%

53- B

54- E

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