Question

3. (5 pt). The adjusted retention times of pentane, hexane and heptane are 4.19, 6.64 and 10.51 min, respectively. What are the retention indices of pentane, hexane and heptane by definition? The retention indices of propanal and butanol are 536 and 675, respectively. What are the adjusted retention times for these compounds? a. b.
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Answer #1

a)

Given

Retention time of alkane

Pentane (5 carbon atom)= 4.19, hexane (6 C)= 6.64, and heptane(7 C) =10.51

According to definition of Kovat’s retention indices for normal alkane is 100 times the number of carbon thus the retention indices are as follows

Pentane (5 carbon atom)= 100 x 5 = 500

hexane (6 C)=100 x 6 =600

heptane(7 C) =100 x 7 = 700

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