Rank the following compounds in order of increasing boiling point and justify your answer.

Question

Question

Answer 1

Answer #1

Boiling point of 3 is greater tha boiling point of 1.

Compound 3 will form intermolecular hydrogen bonding as well as dipole dipole interactions but compound 1 will only form hydrogen bonding.

Boiling point of 1 is greater tha boiling point of 2.

Compound 1 can form hydrogen bonding, whereas 2 cannot form hydrogen bonding, because electronegativity of sulfur is less than oxygen.

Answer 2

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