Synthesize the following compounds starting from benzene. Reactions contain more than two steps. Assume that you can separate ortho and para isomers if necessary ( 36 point).
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Starting with benzene as your only source of aromatic compounds, how would you synthesize the following substances? Assume that you can separate ortho and para isomers if necessary. p-Chlorotoluene m-Bromonitrobenzene o-Bromobenzenesulfonic acid m-Chlorobenzenesulfonic acid Starting with either benzene, phenol, or toluene, how would you synthesize the following substances? Assume that ortho and para isomers can be separated 2-Bromo-4-methylphenol 1,3,5-Trinitrobenzene 2,4,6-Tribromoaniline 2-Chloro-4-nitrotoluene
Starting with benzene and any reagents you need, synthesize compound shown. More than one step is required. Assume you can separate ortho and para-isomers. (12 pts) _CH₂
Starting with Benzene and using any other necessary reagents of your choice a synthesis for the following compound. Assume that ortho and para isomers can be There may be more than one plausible answer.
Aromatic Synthesis Reactions Starting with benzene, propose syntheses to carry out each of the following conversions. Assume ortho and para isomers can be separated.
Ethyl phenylacetate is a pleasant smelling compound used in perfumery. Propose a synthesis starting with benzene. Show all reagents and all intermediate structures. You do not need to show the mechanism. Assume ortho and para isomers can be separated. 3. Ethyl phenylacetate Ethyl phenylacetate is a pleasant smelling compound used in perfumery. Propose a synthesis starting with benzene. Show all reagents and all intermediate structures. You do not need to show the mechanism. Assume ortho and para isomers can be...
17-52 Show how you would synthesize the following compounds, starting with benzene or toluene and any necessary acyclic reagents. Assume para is the major product (and separable from ortho) in ortho, para mixtures. 1-phenyl-1-bromobutane 1-phenyl-1-methoxybutane 3-phenylpropan-1-ol ethoxybenzene 1,2-dichloro-4-nitrobenzene 1-phenylpropan-2-ol p-aminobenzoic acid 2-methyl-1-phenylbutan-2-ol 5-chloro-2-methylaniline 3-nitro-4-bromobenzoic acid 3-nitro-5-bromobenzoic acid 4-butylphenol 2-(4-methylphenyl)butan-2-ol
2. Propose a syntheses of the following compound starting with benzene. Assume ortho and para isomers can be separated. (1 UN ONK , COOH COOH
Homework extra credit! #18. As promised in lecture... Propose a synthesis of this compound starting with the ind se a synthesis of this compound starting with the indicated material. For full credit you need to write out all the steps, showing the reagents used for each reaction. each step. For reactions that produce both ortho and para isomers, assume that the par e both ortho and para isomers, assume that the para isomer is the major product. This is not...
4. Propose an efficient synthesis of the molecule below starting with benzene. You can use any other reagents you want. NOTE: Some reactions produce ortho- and para-products. It is allowable to just take ONE of the products and use it in the next synthesis or claim it as the final product (we assume that ortho- and para-products can be separated). (3 points) CH2CH2CH Br
Question 3 Show how you can synthesize the following compounds using the indicated starting materials and any other necessary substances or reagents. (20 pts) A. CH COOH (starting from ortho-nitrotoluene) B. HN (starting from nitrobenzene)