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Question 3 Show how you can synthesize the following compounds using the indicated starting materials and...
Starting with benzene as your only source of aromatic compounds, how would you synthesize the following substances? Assume that you can separate ortho and para isomers if necessary. p-Chlorotoluene m-Bromonitrobenzene o-Bromobenzenesulfonic acid m-Chlorobenzenesulfonic acid Starting with either benzene, phenol, or toluene, how would you synthesize the following substances? Assume that ortho and para isomers can be separated 2-Bromo-4-methylphenol 1,3,5-Trinitrobenzene 2,4,6-Tribromoaniline 2-Chloro-4-nitrotoluene
17-52 Show how you would synthesize the following compounds, starting with benzene or toluene and any necessary acyclic reagents. Assume para is the major product (and separable from ortho) in ortho, para mixtures. 1-phenyl-1-bromobutane 1-phenyl-1-methoxybutane 3-phenylpropan-1-ol ethoxybenzene 1,2-dichloro-4-nitrobenzene 1-phenylpropan-2-ol p-aminobenzoic acid 2-methyl-1-phenylbutan-2-ol 5-chloro-2-methylaniline 3-nitro-4-bromobenzoic acid 3-nitro-5-bromobenzoic acid 4-butylphenol 2-(4-methylphenyl)butan-2-ol
5. Show how to synthesize the following molecules using the given starting material. Show all the intermediate products for multiple steps. You can use any other reagents or starting materials necessary D amer --
Show how you would use Grignard syntheses to prepare the
following alcohols from the indicated starting materials and any
other necessary reagents. Draw the Grignard reagent and any other
organic reagents needed.
11 RUVIUWI Constans i Pendulu Part F Show how you would use Grignard syntheses to prepare the following alcohols from the indicated starting materials and any other necessary reagents. Draw the Grignard reagent and any other organic reagents needed. ОН -C-CH CH, from C-OCH.CH Draw the molecules on...
Give a reasonable synthesis for
each of the following compounds from the indicated starting
materials. You may use any other organic or inorganic reagents you
wish unless otherwise indicated. The desired product for each
reaction you propose must be the one of the predominant products.
Give the reactants, conditions (where appropriate) and products of
each synthetic step. If equal mixtures are anticipated (i.e. ortho
/ para products) then indicate where separations are needed. NO
MECHANISMS! [6 points
2. Give a...
wing 6 Show how the following compounds could be prepared from the given starting materials. You can use any necessary organic or inorganic reagents. NHCH -NH; CH OH OH ible or an inyersible reaction? Explain.
Synthesize the following reactions using the starting materials
given using any reagents necessary
Using the starting materials on the left of the arrows synthesize
the product on the right using any reagents necessary to complete
the reaction
Noz Br
Noz Br
3. Propose reasonable syntheses of each of the following compounds from the given starting materials. You may use any other readily available alkyl halides, solvents and reagents as necessary. More than one step is necessary. Show all intermediates, reactions, reagents and conditions clearly. It is not necessary to show the mechanism. HCECH HCECH , X HCECH HC=CH M H OHC (30 marks)
Show how you would synthesize the following compound starting
with acetylene and compounds containing no more than two carbon
atoms as organic starting material. You may use any additional
reagents you need
Br H H Br
Starting with nitrobenzene (PhNO2) and using any other inorganic reagents, synthesize phenol (PhOH). Show the conditions and major organic product for each step.