Question

8. Provide the major organic product which results when PhCH2CH2CO2H is treated with 2 eq. butyllithium followed by H30+. 9. Provide the major organic product which results when (CH3)2CHCH2CH2COCI is treated with LIAIH[OC(CH3)313-

Answer 1

W a Ph CH2 CH2 C-OH - açidic Buti acidic ń i Ph CH2 CH2-c-oki abstraction Buki WW.SINGH Bocor Ph CH 2 CHE <H30 H -A20 Ph CH2 CH2-C- ware-OH ... PHCH2 CH2-ca But Bu Product Major t a + KiAlH [oc (CH3)3] 37 * CCHB). CH CH₂ CH2-coat unlike LiAlH4 Lithium-Tri-tert- - butony aluminium hydride i, e LiAlH [OC C CH3)3] is a (CH3)₂ CH CH 2 CH 2 CH more controlled reducing trice Alloc (CH3)3] agent, as t, as it has only one 't to give. + Scanned with CamScanner

Mechanism ? continou. (443), CH CH2 CH2-CF4 H -Aliöt OP KPⓇ ( g), 내 다 다 Cs (CH3)2 CH CH2 CH2-C-H mayor product Hany Site + Kid + Ai [occells) 27. barbie van cs Scanned with CamScanner