3. Indicate the multiplicity for all nonequivalent H's in the following molecules. ICH CH2CHBr2 H3C CH...
3. Assign R or Sconfiguration to the following molecules: Br F н. F Br Br -CH. CH=CH, H CH,CH CH2CH3 CH,CH, -CHE OH -CH=CH2 H3C CH, HI CH(CH3)2
'HNMR - Problem Set-3 How would you distinguish between the compounds in each of the following pairs by 'H NMR? a. CH CH2CH2OCH; and CH3CH2OCH2CH3 b. BrCH CH CH Br and BrCH2CH2CH NO2 CH3 CH3 c. CH:CH-CHCH; and CH3 CH CH CH3 CH CH d. CH3-C-C-OCH; CH OCH and CH3-C-CH; OCH e. H3C CH; -C-CH3 CH; and -CHỤCCH CH 'HNMR-Problem Set-3 (Page 1 of 2) Name Write the structural formula for each of the following compounds from the 'H NMR...
7. Which compound below be H-1 NMR 0.9 ppm (quartet fits the following spectral data? (6 points) 1.2 ppm (sextet 2 hydrogens), 2.1 ppm (triplet, hydrogens), 4.3 ppm (singlet 3 hydrogens) C-13 NMR 5 signals 25 ppr ppm (CH2); 61 ppm: (CH3) 198 Ppm (C). IR strong peak 1735 cm Ignals 25 ppm (CH): 35 ppm (CH2), 46 ppm (CH2); 61 ppm: em Mass Spee parent M+ = 102 Mass Spec paren ou 0 H2 CH3 HjC Holo H3C- CC...
Question 3 1/1 pts Consider the following molecules. CHCH; CH; - CH3-CH2-CEC-CH-CH3 CH-CH-CH-CH-CH, CH; Structure C is classified as a(n) alkene alkane cycloalkane alkyne aromatic compound
NMR Exercise Lab Determine the structure of the following unknown organic compounds from the 'H and C NM below. When supplying spectroscopic information for parts b-c below, be sure to give units appropriately when identifying specific peaks in a spectrum that are associated with specific portions of the structural formula that you give in part a. (a) Provide a structural formula which is consistent with all of the given information; give the degrees of unsaturation (DoU). (b) For the 15'C...
PART 1 - For the following compounds A. Predict how many signals would be detected in the expected 'H NMR spectrum. B. Label proton groups and determine their multiplicity. c. Predict the chemical shifts of each signal in the expected 'H NMR spectrum of the following compounds from the correlation chart in the last page. <Example> Number of signals O Proton groups Multiplicity Triplet B Multiplet (sextet) c Triplet D Singlet Chemical Shirt (ppm) 0.8-1.0 1.2 - 1.5 3.2 4.0...
3. For each of the following chiral molecules, indicate whether the enantiomer shown is the Ror Senantiomer. CH3 CH2-CHE чон NH, OH CH=CH2 4. A liquid mixture is comprised of a 50:50 mixture of the following two compounds. Which of the following statements is true? (Choose one) CH3 A) The liquid is a racemate. B) The liquid is a mixture of two constitutional isomers. C) The liquid is a mixture of two unrelated compounds. D) The compounds are identical; it...
determine the structure of your unknown from the molecular formula, IR, and 13C NMR spectra. assign all of your 13C NMR absorptions. IR & 1C NMR Lab Unknown Your group's mission is to determine the structure of your unknown from the molecular forrmula, IR and 13C NMR spectra. Assign all of your C NMR absorptions. You want to know which resonances correspond to which parts of the product's structure. The best way to do this is to draw a picture...
for the following 2 compounds, please calculate, and show the calculations for, the degree of unsaturation, assign the IR spectrum peaks, assign the 13C NMR peaks, assign the 1H NMR peaks, and draw the structure for the unknown compound. CHIM 245 Spectroscopy Problem Set #2 In this problem set there are two unknown compounds. You are provided with the formula, IR spectrum, "C NMR spectrum, and 'H NMR spectrum for each compound. Each unknown is worth 10 points, with an...
7. Which compound below best fits the following spectral data? 8. How many signals would you expect to see in the broadband decoupled C^13 spectra of the following compounds? 9. If a proton gave an NMR signal at 3.2 ppm on a MHz NMR, what would the chemical shift be of this proton (in ppm) if the sample was run in 400 MHz NMR? 7. Which compound below best fits the following spectral data? (6 points) H-1 NMR 0.9 ppm...