Question

(1) Identify each of the following half-reactions as either an oxidation half-reaction or a reduction half-reaction. half-reaWhen the following half reaction is balanced under acidic conditions, what are the coefficients of the species shown? NO3 + H

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Answer #1

1)

Reduction: Addition of electron

Oxdation: Loss of electron

Cr^{3+}(aq)+ 3e^- \rightarrow Cr(s) ...........Reduction

Al(s)\rightarrow Al(aq) +3e^- ...........oxidation

2)

Oxiadtion half reaction + Reduction half reaction=>

Cr^{3+}+Al(s)\rightarrow Cr(s)+Al^{3+}(aq) ----> \text{Balanced redox reaction}

BALANACING IN ACIDIC MEDIUM:

i. Balance the metal first

ii. Balance oxygen atom by adding H2O on that side in which it has less number of oxygen atom

iii. To balance hydrogen atom, add twice H+ on the other side of H2O added in above step

iv. Balance charge by adding e- on required side

3)

NO_3^-\rightarrow NO

=>NO_3^-\rightarrow NO + 2H_2O

=>NO_3^- +4H^+\rightarrow NO + 2H_2O

Oxidation state of N channges from +5 to +2

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