The hydroxyaldehyde shown cyclizes to form a hemiacetal under acidic or basic conditions. Use wedge-dot structures...
The hydroxyaldehyde shown cyclizes to form a hemiacetal under acidic or basic conditions. Use wedge- dot structures to draw the two stereoisomers formed from the aldehyde when it cyclizes. Explain if the relationship between the products. Is the product mixture expected to be optically active or optically inactive? HOH H3C-©CH2CH2C
QUESTION 1 Any reaction involving a carbonyl group and a strong acid begins with the same first step, which is __________________ of the carbonyl oxygen. QUESTION 2 Using condensed molecular formulas (C#H#X#Y#) for your answers, predict the products of the reactions of C6H5CH2CHO (phenylacetaldehyde) with these reagents, and identify the functional group produced in the product. Note that the Tx symbol above allows you to do a subscript. a. NaBH4 / CH3OH b. 1. CH3MgBr; 2. H2O c. Ph3P=CHCH3 d....
Hemiacetal formation occurs under acidic, basic, and neutral conditions. Under what set of conditions will acetal formation not occur?
In the box provided, draw the two stereochemical products formed when the ketone shown is reduced with sodium borohydride followed by water. Show correct stereochemistry using wedge-dot structures.I need to see the mechanism for this.3 (4).jpg
- Part A Draw the products formed when the structure shown below undergoes hydrolysis. Interactive 3D display mode Draw the molecules on the canvas by choosing buttons from the Tools (for bonds), Atoms, and Advanced Template toolbars. The single bo active by default. D ®. H200 ml HO O+ 23 Iooooood O Almost right! Normally, an acetal hydrolyzes to a carbonyl compound (ketone or aldehyde) and an alcohol under acidic conditions. In this particular case, though, entropy causes the hydroxy...
Assume that the compound depicted above was formed under acidic conditions, was the major product obtained after purification (> 70%), and was isolated as a mixture of diastereomers. Is it possible to know with absolute certainty that the immediate precursor featured the 6-membered ring that is seen in the product? Indicate your answer by circling the appropriate word below. YES NO Explain your reasoning. Your answer should contain sufficient detail to persuade a scholar of organic chemistry. The best answers...
a. Caffeine can be protonated under acidic conditions to form an imidazolium-like species. Draw the structure for this protonated form, then find and report a pKa value for the most acidic proton. b. Draw a reaction scheme between caffeine and water. Which side of the equilibrium is favored for this acid/base reaction? Hint: Use the pKa value from part a. c. Find and report a pKa value for phenol. Draw a reaction scheme between phenol and water. Which side of...
2. A reaction discussed in class involved treating a primary amine with chloroform under basic! conditions to form an isocyanide. When a secondary amine was used instead, an amide was formed: NaOH NaOH CHCIE R-NEC + CHCIE RNH2 + Lº amine RỌNH 2° amine HANR2 2. A reaction discussed in class involved treating a primary amine with chloroform under basic conditions to form an isocyanide. When a secondary amine was used instead, an amide was formed: NaOH NaOH CHCIE R-NEC...
Help 1. Under acidic conditions, if Z CH3 in Compound 2, Compound 1 forms. он он о 2 3 a. If ZCompound 3 forms Identify Z and determine reaction condition A. b. Use curved arrows to show how Compound 3 forms from Compound 2 using your Z and reaction condition A from Question 1a c. How does Z determine the product that forms? 2. Ambien is a prescription sedative. Draw the structures of the metabolic (hydrolysis under acid conditions) products...
please help with all of the question. The following skeletal oxidation-reduction reaction occurs under acidic conditions. Write the balanced REDUCTION half reaction. NO3 + Mn2 MnO4 +HNO2 Reactants Products Retry Entire Group 9 more group attempts remaining Submit Answer Mastered The following skeletal oxidation-reduction reaction occurs under basic conditions. Write the balanced REDUCTION half reaction. Sio2 + Ag Ag2O+Si- Products Reactants (1) Identify each of the following half-reactions as either an oxidation half-reaction or a reduction half-reaction half-reaction identification AP...